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The products for the following reactions...

The products for the following reactions are
(i) `CH_(3)-underset(H)underset(|)overset(Br)overset(|)(C)-CH_(2)-CH_(3)+"alc. KOH"to X`
(ii) `CH_(3)-underset(CH_(3))underset(|)(C)H-CH=CH_(2) overset(O_(3))to Y+Z`

A

`X=(CH_(3))_(2)C=CH_(2),Y=CH_(3)CH_(2)CHO,Z=CH_(3)CH_(2)CHO`

B

`X=CH_(2)=CH_(2),Y=CH_(3)CHO,Z=CH_(3)COOH`

C

`X=CH_(3)-CH=CH-CH_(3)`
`Y=CH_(3)-overset(CH_(3))overset(|)(C)H-CHO,Z=HCHO`

D

`X=CH_(3)-CH=C(CH_(3))_(2),Y=HCHO,Z=CH_(3)CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the reactions given in the question, we will analyze each reaction step by step. ### Reaction (i): **Given Reaction:** \[ \text{CH}_3-\text{C}(\text{Br})-\text{CH}_2-\text{CH}_3 + \text{alc. KOH} \rightarrow X \] **Step 1: Identify the Reactants** - The reactant is 1-bromo-2-butane (CH3-CHBr-CH2-CH3) and alcoholic KOH. **Step 2: Understand the Role of Alcoholic KOH** - Alcoholic KOH is a strong base and will facilitate elimination reactions (dehydrohalogenation) rather than substitution. **Step 3: Formation of Carbocation** - The base (OH-) will abstract a proton (H+) from the carbon adjacent to the carbon bearing the bromine (Br). This leads to the formation of a carbocation. - The more stable carbocation (secondary) will form at the carbon adjacent to the bromine. **Step 4: Elimination Reaction** - The bromine (Br) will leave, and a double bond will form between the carbons, resulting in the formation of an alkene. **Step 5: Write the Product** - The product formed is 2-butene (CH3-CH=CH-CH3). - Therefore, \( X = \text{CH}_3-\text{CH}=\text{CH}-\text{CH}_3 \). ### Reaction (ii): **Given Reaction:** \[ \text{CH}_3-\text{C}(\text{CH}_3)-\text{CH}=\text{CH}_2 + \text{O}_3 \rightarrow Y + Z \] **Step 1: Identify the Reactants** - The reactant is 3-methyl-1-butene (CH3-CH(CH3)-CH=CH2) and ozone (O3). **Step 2: Understand Ozonolysis** - Ozonolysis involves the cleavage of double bonds in the presence of ozone, resulting in the formation of carbonyl compounds. **Step 3: Break the Double Bond** - The double bond between the carbons will break, and oxygen will be added to the resulting fragments. **Step 4: Write the Products** - The ozonolysis of 3-methyl-1-butene will yield two products: - 2-methylpropanal (from the carbon chain with the methyl group). - Formaldehyde (HCHO) from the other fragment. Thus, the products are: - \( Y = \text{2-methylpropanal} \) - \( Z = \text{formaldehyde (HCHO)} \) ### Final Answers: - \( X = \text{CH}_3-\text{CH}=\text{CH}-\text{CH}_3 \) (2-butene) - \( Y = \text{2-methylpropanal} \) - \( Z = \text{formaldehyde (HCHO)} \)

To solve the reactions given in the question, we will analyze each reaction step by step. ### Reaction (i): **Given Reaction:** \[ \text{CH}_3-\text{C}(\text{Br})-\text{CH}_2-\text{CH}_3 + \text{alc. KOH} \rightarrow X \] **Step 1: Identify the Reactants** - The reactant is 1-bromo-2-butane (CH3-CHBr-CH2-CH3) and alcoholic KOH. ...
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