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How many structures are possible for C(5...

How many structures are possible for `C_(5)H_(8)` with one triple bond?

A

4

B

3

C

2

D

1

Text Solution

AI Generated Solution

The correct Answer is:
To determine how many structures are possible for the hydrocarbon \( C_5H_8 \) with one triple bond, we can follow these steps: ### Step 1: Calculate the Degree of Unsaturation (DU) The degree of unsaturation can be calculated using the formula: \[ DU = \frac{1}{2} \left( 2C + 2 - H \right) \] where \( C \) is the number of carbon atoms and \( H \) is the number of hydrogen atoms. For \( C_5H_8 \): \[ DU = \frac{1}{2} \left( 2 \times 5 + 2 - 8 \right) = \frac{1}{2} \left( 10 + 2 - 8 \right) = \frac{1}{2} \times 4 = 2 \] ### Step 2: Understand the Implications of DU A degree of unsaturation of 2 indicates that there are either: - Two double bonds, or - One triple bond, or - One double bond and one ring, or - Two rings. Since we are looking for structures with one triple bond, we will focus on that. ### Step 3: Identify Possible Structures with One Triple Bond 1. **Structure 1**: - **Linear structure**: \( CH \equiv C - CH_2 - CH_2 - CH_3 \) - This structure has the triple bond between the first and second carbon. 2. **Structure 2**: - **Linear structure**: \( CH_2 - C \equiv C - CH_2 - CH_3 \) - This structure has the triple bond between the second and third carbon. 3. **Structure 3**: - **Branched structure**: \( CH_3 - CH_2 - C \equiv C - CH_3 \) - This structure has the triple bond between the third and fourth carbon. ### Step 4: Check for Identical Structures - The first and second structures are unique due to the position of the triple bond. - The third structure is also unique as it has a branched configuration. ### Step 5: Conclusion After analyzing the structures, we find that there are **three distinct structures** for \( C_5H_8 \) with one triple bond. ### Final Answer Thus, the number of structures possible for \( C_5H_8 \) with one triple bond is **3**. ---

To determine how many structures are possible for the hydrocarbon \( C_5H_8 \) with one triple bond, we can follow these steps: ### Step 1: Calculate the Degree of Unsaturation (DU) The degree of unsaturation can be calculated using the formula: \[ DU = \frac{1}{2} \left( 2C + 2 - H \right) \] where \( C \) is the number of carbon atoms and \( H \) is the number of hydrogen atoms. ...
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NCERT FINGERTIPS ENGLISH-HYDROCARBONS -Assertion And Reason
  1. How many structures are possible for C(5)H(8) with one triple bond?

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  2. Assertion: 2,2-Dimethylbutane does not have any tertiary carbon atom. ...

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  3. Assertion: The reaction, C(2)H(5)Br +2Na+C(2)H(5)Br to C(4)H(10)+2NaBr...

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  4. Assertion: Wurtz reaction is not preferred for the preparation of alka...

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  5. Assertion: Sodium salt of butanoic acid on heating with soda lime give...

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  6. Assertion: Boiling point of pentane is higher than 2,2-dimethylpropane...

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  7. Assertion: Iodination of alkanes is carried out in the presence of oxi...

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  8. Assertion: Staggered conformation of ethane is most stable while eclip...

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  9. Assertion: cis-form of alkene is found to be more polar than the trans...

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  10. Assertion: Alkenes are easily attacked by electrophilic reagents. Re...

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  11. Assertion: Addition of HBr to propene yields 2-bromopropane but in pre...

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  12. Assertion: Decolourisation of KMnO(4) solution is used as a test for u...

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  13. Assertion: Ethyne reacts with sodium metal and sodamide to form sodium...

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  14. Assertion: Cyclopentadienyl anion is aromatic in nature. Reason: Cyc...

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  15. Assertion: The second substituent may enter the mono-substituted benze...

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  16. Assertion: In case of aryl halides, halogens are moderately deactivati...

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