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Assertion: The reaction, C(2)H(5)Br +2Na...

Assertion: The reaction, `C_(2)H_(5)Br +2Na+C_(2)H_(5)Br to C_(4)H_(10)+2NaBr` is known as Wurtz reaction.
Reason: The reaction is carried out in presence of dry ether.

A

If both assertion and reson are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Assertion The assertion states that the reaction: \[ C_2H_5Br + 2Na \rightarrow C_4H_{10} + 2NaBr \] is known as the Wurtz reaction. **Explanation**: - The Wurtz reaction involves the coupling of alkyl halides (in this case, ethyl bromide, \(C_2H_5Br\)) in the presence of sodium metal to form higher alkanes (in this case, butane, \(C_4H_{10}\)). - The reaction proceeds through the formation of free radicals, which then couple to form the alkane. ### Step 2: Understanding the Reason The reason states that the reaction is carried out in the presence of dry ether. **Explanation**: - Dry ether is used as a solvent in the Wurtz reaction because it prevents the formation of alcohols that would occur if water were present. - In the presence of water, the sodium would react with water instead of the alkyl halide, leading to the formation of alcohols rather than the desired alkane. ### Step 3: Conclusion Both the assertion and the reason are correct. The reaction described is indeed the Wurtz reaction, and it is correctly carried out in the presence of dry ether. ### Final Answer: **Both the assertion and the reason are true, and the reason correctly explains the assertion.** ---
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