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Assertion: Sodium salt of butanoic acid ...

Assertion: Sodium salt of butanoic acid on heating with soda lime gives butane.
Reason: Decarboxylation reaction yields alkanes having same number of carbon atoms as the parent acid.

A

If both assertion and reson are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve this assertion-reason question, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Assertion The assertion states that "Sodium salt of butanoic acid on heating with soda lime gives butane." - Butanoic acid has the formula CH₃CH₂CH₂COOH, which has four carbon atoms. - When the sodium salt of butanoic acid (CH₃CH₂CH₂COONa) is heated with soda lime (a mixture of sodium hydroxide and calcium oxide), a decarboxylation reaction occurs. - During decarboxylation, the carboxyl group (-COOH) is removed as carbon dioxide (CO₂), resulting in a hydrocarbon with one less carbon atom than the original acid. ### Step 2: Decarboxylation Reaction In this case, the sodium salt of butanoic acid (C₄H₈O₂) will lose one carbon atom during the decarboxylation process: - The reaction can be represented as: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{COONa} \xrightarrow{\text{soda lime}} \text{C}_3\text{H}_8 + \text{Na}_2\text{CO}_3 \] - The product formed is propane (C₃H₈), not butane (C₄H₁₀). Therefore, the assertion is **false**. ### Step 3: Understanding the Reason The reason states that "Decarboxylation reaction yields alkanes having the same number of carbon atoms as the parent acid." - This statement is also incorrect because, during decarboxylation, one carbon atom is removed from the parent acid. - Thus, the product will have one less carbon atom than the original acid. ### Conclusion Both the assertion and the reason are false. ### Final Answer - Assertion: False - Reason: False

To solve this assertion-reason question, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Assertion The assertion states that "Sodium salt of butanoic acid on heating with soda lime gives butane." - Butanoic acid has the formula CH₃CH₂CH₂COOH, which has four carbon atoms. - When the sodium salt of butanoic acid (CH₃CH₂CH₂COONa) is heated with soda lime (a mixture of sodium hydroxide and calcium oxide), a decarboxylation reaction occurs. - During decarboxylation, the carboxyl group (-COOH) is removed as carbon dioxide (CO₂), resulting in a hydrocarbon with one less carbon atom than the original acid. ...
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