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In the following reacton, product P is ...

In the following reacton, product P is
`R-overset(O)overset(||)C-Cloverset(H_(2))underset(Pd-BaSO_(4))rarrP`

A

RCHO

B

`RCH_(3)`

C

RCOOH

D

`RCH_(2)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product P in the given reaction, we need to analyze the reaction step by step. ### Step 1: Identify the starting material The starting material in the reaction is an acid chloride, represented as R-C(=O)Cl. Acid chlorides are reactive compounds that can be converted into various functional groups. **Hint:** Acid chlorides have the general structure R-C(=O)Cl, where R is an alkyl or aryl group. ### Step 2: Understand the reaction conditions The reaction is carried out in the presence of H2 and Pd/BaSO4. This indicates that we are dealing with a Rosenmund reduction, which is a specific type of reduction that converts acid chlorides to aldehydes. **Hint:** The presence of Pd/BaSO4 is crucial as it controls the extent of reduction, preventing further reduction to alcohol. ### Step 3: Apply the Rosenmund reduction mechanism In the Rosenmund reduction, the acid chloride (R-C(=O)Cl) reacts with hydrogen (H2) in the presence of palladium on barium sulfate (Pd/BaSO4). The palladium acts as a catalyst, and the barium sulfate serves to limit the reaction, ensuring that the product is an aldehyde rather than a primary alcohol. **Hint:** Remember that the Rosenmund reduction specifically converts acid chlorides to aldehydes without further reducing them to alcohols. ### Step 4: Determine the product The product of the reaction is an aldehyde, which can be represented as R-C(=O)H. This product retains the same carbon skeleton as the starting acid chloride but has been converted to an aldehyde. **Hint:** Aldehydes have the general structure R-C(=O)H, where R is the same as in the acid chloride. ### Conclusion Thus, the product P in the reaction is an aldehyde, specifically R-C(=O)H. **Final Answer:** The product P is R-C(=O)H (an aldehyde).
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Knowledge Check

  • In the following reaction product 'P' is R-overset(O)overset(||)C-Clunderset(BaSO_(4))overset(H_(2))toP .

    A
    `RCH_(2)OH`
    B
    `RCOOH`
    C
    `RCHO`
    D
    `RCH_(3)`
  • In the following reaction product 'P' is R-overset(O)overset(||)C-Clunderset(BaSO_(4))overset(H_(2))toP .

    A
    `RCH_(2)OH`
    B
    `RCOOH`
    C
    `RCHO`
    D
    `RCH_(3)`
  • In the following reaction product 'P' is R-overset(O)overset(||)C-Clunderset(BaSO_(4))overset(H_(2))toP .

    A
    `RCH_(2)OH`
    B
    `RCOOH`
    C
    `RCHO`
    D
    `RCH_(3)`
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