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The final product (C ) obtained in the r...

The final product (C ) obtained in the reaction sequence is
`CH_(3)CH_(2)COOH overset(PCl_(3))to(A)overset(C_(6)H_(6))underset(AlCl_(3))to(B)overset(NH_(2)NH_(2))underset("base, heat")to(C )`

A

B

C

D

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AI Generated Solution

The correct Answer is:
To solve the given reaction sequence, we will go through each step systematically. ### Step 1: Reaction of Propanoic Acid with PCl3 The first step involves the reaction of propanoic acid (CH₃CH₂COOH) with phosphorus trichloride (PCl₃). **Reaction:** \[ \text{CH}_3\text{CH}_2\text{COOH} + \text{PCl}_3 \rightarrow \text{CH}_3\text{CH}_2\text{C(=O)Cl} + \text{HCl} + \text{POCl}_3 \] **Product A:** The product formed is propanoyl chloride (CH₃CH₂C(=O)Cl). ### Step 2: Friedel-Crafts Acylation Next, we take the product A (propanoyl chloride) and react it with benzene (C₆H₆) in the presence of anhydrous aluminum chloride (AlCl₃). This reaction is known as Friedel-Crafts acylation. **Reaction:** \[ \text{CH}_3\text{CH}_2\text{C(=O)Cl} + \text{C}_6\text{H}_6 \xrightarrow{\text{AlCl}_3} \text{C}_6\text{H}_5\text{C(=O)CH}_2\text{CH}_3 + \text{HCl} \] **Product B:** The product formed is phenyl propanoyl (C₆H₅C(=O)CH₂CH₃). ### Step 3: Hydrazine Reaction In the final step, we react product B (phenyl propanoyl) with hydrazine (NH₂NH₂) in the presence of a base and heat. This reaction is known as the Wolff-Kishner reduction. **Reaction:** \[ \text{C}_6\text{H}_5\text{C(=O)CH}_2\text{CH}_3 + \text{NH}_2\text{NH}_2 \xrightarrow{\text{Base, Heat}} \text{C}_6\text{H}_5\text{CH}_2\text{CH}_3 + \text{N}_2 + \text{H}_2\text{O} \] **Product C:** The final product C is phenyl ethane (C₆H₅CH₂CH₃). ### Summary of Products: - Product A: Propanoyl chloride (CH₃CH₂C(=O)Cl) - Product B: Phenyl propanoyl (C₆H₅C(=O)CH₂CH₃) - Product C: Phenyl ethane (C₆H₅CH₂CH₃) ### Final Answer: The final product (C) obtained in the reaction sequence is **C₆H₅CH₂CH₃**. ---

To solve the given reaction sequence, we will go through each step systematically. ### Step 1: Reaction of Propanoic Acid with PCl3 The first step involves the reaction of propanoic acid (CH₃CH₂COOH) with phosphorus trichloride (PCl₃). **Reaction:** \[ \text{CH}_3\text{CH}_2\text{COOH} + \text{PCl}_3 \rightarrow \text{CH}_3\text{CH}_2\text{C(=O)Cl} + \text{HCl} + \text{POCl}_3 \] ...
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NCERT FINGERTIPS ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-MCQs(CHEMICAL REACTIONS )
  1. Which of the following compounds would have the smallest value for pK(...

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  2. -OH group present in alcohols is neutral white it is acidic in carboxy...

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  3. Which of the following is the correct order of relative strength of ac...

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  4. Which of the following orders is not correct for the decreasing order ...

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  5. In a set of the given reactions, acetic acid yielded a product iC. CH...

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  6. Identify the compounds (X), (Y) and (Z) in the following reaction : ...

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  7. Identify (X), (Y) andc (Z) in the given reaction : CH(3)CHO overset(...

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  8. Complete the missing lnks (X), (Y) and (Z) by making an appropriate c...

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  9. What happens when a carboxylic acid is treated with lithium aluminum h...

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  10. A compound (X) having molecualr formula C(4)H(8)O(2) is hydrolysed by ...

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  11. A compound (X) with a molecualr formula C(5)H(10)O gives a positive 2...

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  12. Fill in the blanks. In Hell-Volhard-Zelinsky reaction, the carboxyli...

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  13. Acetic acid can be halogenated in presence of phosphorus and chlorine....

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  14. Which of the following will not undergo HVZ reaction ?

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  15. Which of the following statements is correct regarding formic acid ?

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  16. Match the column I with column II and mark the appropriate choice .

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  17. The major product of the following reaction is: CH(3)-underset(H)und...

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  18. The final product (C ) obtained in the reaction sequence is CH(3)CH(...

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