Home
Class 12
CHEMISTRY
In Clemmensen reduction carbonyl compoun...

In Clemmensen reduction carbonyl compound is treated with ________.

A

zinc amalgam + HCl

B

sodium amalgam + HCl

C

zinc amalgam + nitric acid

D

sodium amalgam + `HNO_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding Clemmensen Reduction**: Clemmensen reduction is a chemical reaction that involves the reduction of carbonyl compounds (aldehydes and ketones) to alkanes. This reaction is particularly useful for converting carbonyl groups into methylene groups. 2. **Reagents Used**: The key reagents in the Clemmensen reduction are zinc amalgam and hydrochloric acid (HCl). Zinc amalgam is a mixture of zinc and mercury, which serves as the reducing agent. 3. **Mechanism Overview**: In the presence of zinc amalgam and HCl, the carbonyl compound undergoes reduction. The carbonyl group (C=O) is converted into a methylene group (C-H2), effectively removing the oxygen and adding hydrogen. 4. **Example Reaction**: For instance, if we take acetone (CH3C(=O)CH3) as a carbonyl compound, the Clemmensen reduction will convert it into propane (CH3CH2CH3). During this process, water (H2O) is also produced as a byproduct. 5. **Conclusion**: Therefore, in the Clemmensen reduction, the carbonyl compound is treated with zinc amalgam and hydrochloric acid (HCl). **Final Answer**: In Clemmensen reduction, carbonyl compound is treated with **zinc amalgam and hydrochloric acid (HCl)**. ---
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    NCERT FINGERTIPS ENGLISH|Exercise ASSERTION & REASON|15 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    NCERT FINGERTIPS ENGLISH|Exercise Nomenclature And Structure Of Carbonyl Group|3 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    NCERT FINGERTIPS ENGLISH|Exercise MCQs(CHEMICAL REACTIONS )|18 Videos
  • ALCOHOLS,PHENOLS AND ETHERS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|14 Videos
  • AMINES

    NCERT FINGERTIPS ENGLISH|Exercise ASSERTION & REASON CORNER|14 Videos

Similar Questions

Explore conceptually related problems

In Clemmensen's reduction , the catalyst used is

Ozone give carbonyl compounds with :

(a) Illustrate the following name reactions by giving example : (i) Cannizzaro's reaction (ii) Clemmensen reduction (b) An organic compound A contains 69.77 % carbon , 11.63 % hydrogen and rest oxygen . The molecular mass of the compound is 86. it does not reduce Tollen's reagent but forms an addition compound with sodium hydrogen sulphite and give positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acid. Derive the possible structure of compound A .

Clemmensen's reduction will convert cyclohexanone into:

Which of the following carbonyl compounds will react readily with H^+ ?

Which type of reaction in the reduction of carbonyl compound with LAH and NaBH_(4) occurs, and which nucleophile takes part in the reaction?