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Assertion : Aromatic aldehydes and forma...

Assertion : Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction.
Reason : Those aldehydes which have `alpha`-H atom undergo Cannizzaro reaction.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided: **Assertion:** Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction. **Reason:** Those aldehydes which have alpha-H atom undergo Cannizzaro reaction. ### Step-by-Step Solution: 1. **Understanding Cannizzaro Reaction:** - The Cannizzaro reaction is a redox reaction that occurs with aldehydes that do not have an alpha-hydrogen atom. In this reaction, one molecule of the aldehyde is oxidized to a carboxylic acid, while another molecule is reduced to an alcohol. 2. **Identifying Aromatic Aldehydes and Formaldehyde:** - Aromatic aldehydes include compounds like benzaldehyde (C6H5CHO), which lacks an alpha-hydrogen atom because the carbon adjacent to the carbonyl group (the carbonyl carbon) is part of the aromatic ring. - Formaldehyde (HCHO) also does not have an alpha-hydrogen atom as it has no carbon atoms adjacent to the carbonyl carbon. 3. **Analyzing the Assertion:** - Since both aromatic aldehydes (like benzaldehyde) and formaldehyde lack alpha-hydrogens, they can undergo the Cannizzaro reaction. Therefore, the assertion is **correct**. 4. **Analyzing the Reason:** - The reason states that aldehydes with alpha-hydrogen atoms undergo the Cannizzaro reaction. This is **incorrect**. Aldehydes that have alpha-hydrogens typically undergo aldol condensation reactions instead of Cannizzaro reactions. 5. **Conclusion:** - The assertion is true, while the reason is false. Therefore, the correct answer is that the assertion is correct, but the reason is incorrect. ### Final Answer: - Assertion is true, Reason is false.

To solve the question, we need to analyze the assertion and the reason provided: **Assertion:** Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction. **Reason:** Those aldehydes which have alpha-H atom undergo Cannizzaro reaction. ### Step-by-Step Solution: 1. **Understanding Cannizzaro Reaction:** ...
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