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CH(3)CHO+HCHOoverset("dil. NaOH")underse...

`CH_(3)CHO+HCHOoverset("dil. NaOH")underset("Heat")rarrAoverset("HCN)underset(H_(3)O^(+))rarrB`
the structure of compound B is

A

`CH= CH - underset(OH) underset(|)CH- COOH`

B

` CH_(2) = CH- underset(CN) underset(|)CH - OH`

C

` CH_(3)CH_(2) - underset(OH) underset(|) CH - COOH`

D

`CH_(3)- underset(OH) underset(|)CH- COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reactions taking place and derive the structure of compound B. ### Step 1: Identify the Reactants The reactants in the given reaction are: - Acetaldehyde (CH₃CHO) - Formaldehyde (HCHO) ### Step 2: Understand the Reaction Conditions The reaction is carried out in the presence of dilute sodium hydroxide (NaOH) and heat. This indicates that we are performing an aldol condensation reaction. ### Step 3: Perform Aldol Condensation In the aldol condensation, acetaldehyde and formaldehyde react to form a β-hydroxy aldehyde (compound A). The reaction can be summarized as follows: 1. Acetaldehyde (CH₃CHO) reacts with formaldehyde (HCHO) in the presence of NaOH and heat. 2. The product formed (A) is a β-hydroxy aldehyde. The structure of compound A can be represented as: - CH₂(OH)-CH(CH₃)-CHO ### Step 4: Reaction with HCN Next, compound A reacts with hydrocyanic acid (HCN). The cyanide ion acts as a nucleophile and attacks the electrophilic carbonyl carbon of the aldehyde group in compound A. ### Step 5: Formation of Compound B The product formed after the nucleophilic attack is a cyanohydrin. The structure of compound B will have a hydroxyl group (-OH) and a cyano group (-CN) attached to the same carbon. ### Step 6: Hydrolysis of Compound B Finally, the cyanohydrin undergoes acidic hydrolysis in the presence of H₃O⁺. The cyano group (-CN) is converted into a carboxylic acid (-COOH) group. The final structure of compound B can be represented as: - CH₂=CH-COOH (with an -OH group attached to the carbon adjacent to the carboxylic acid). ### Final Structure of Compound B The final structure of compound B is: - **CH₂=CH-COOH**
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NCERT FINGERTIPS ENGLISH-PRACTICE PAPER -1-Practice Paper 1
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