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Identify 'Z' in the reaction given below...

Identify 'Z' in the reaction given below:
`CH_(3)CHO overset(MnO_(4)^(-))underset(dil.H_(2)SO_(4))rarrXoverset(SOCl_(2))rarrYoverset(CH_(3)COONa)rarrZ`

A

`CH_(3)COCH_(2)COONa`

B

`(CH_(3)CO)_(2)O`

C

`CH_(3)CO-O-COCH_(2)CI`

D

`CH_(3)CO-O-COCHCI_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To identify 'Z' in the given reaction sequence, we will follow the steps outlined in the question. ### Step 1: Identify the starting compound The starting compound is acetaldehyde, represented as CH₃CHO. ### Step 2: Reaction with KMnO₄ in dilute H₂SO₄ Acetaldehyde (CH₃CHO) is treated with potassium permanganate (KMnO₄) in the presence of dilute sulfuric acid (H₂SO₄). KMnO₄ is a strong oxidizing agent and will oxidize the aldehyde group (-CHO) to a carboxylic acid group (-COOH). **Product formed (X):** - The oxidation of acetaldehyde leads to the formation of acetic acid (CH₃COOH). ### Step 3: Reaction of acetic acid with SOCl₂ Next, acetic acid (X) reacts with thionyl chloride (SOCl₂). This reaction converts the carboxylic acid into an acyl chloride. **Product formed (Y):** - The reaction of acetic acid with SOCl₂ produces acetyl chloride (CH₃COCl). ### Step 4: Reaction of acetyl chloride with sodium acetate Now, acetyl chloride (Y) reacts with sodium acetate (CH₃COONa). In this reaction, the acetate ion (CH₃COO⁻) acts as a nucleophile and attacks the carbonyl carbon of acetyl chloride. **Product formed (Z):** - This reaction leads to the formation of acetic anhydride (CH₃CO)₂O. ### Final Answer Thus, the compound 'Z' formed in the reaction sequence is acetic anhydride, represented as (CH₃CO)₂O. ---
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