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White phosphorus when reacts with nitric...

White phosphorus when reacts with nitric acid gives

A

`H_(4)P_(2)O_(6)`

B

`H_(3)PO_(2)`

C

`H_(3)PO_(4)`

D

`H_(3)PO_(3)`

Text Solution

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The correct Answer is:
To answer the question regarding the reaction of white phosphorus with nitric acid, we can break down the process step by step. ### Step 1: Identify the Reactants White phosphorus (P4) is the reactant that we are considering. It is a molecular form of phosphorus that is highly reactive. **Hint:** Remember that white phosphorus is often represented as P4 and is known for its reactivity, especially with oxidizing agents. ### Step 2: Reaction with Nitric Acid When white phosphorus reacts with nitric acid (HNO3), it undergoes oxidation. Nitric acid is a strong oxidizing agent that can oxidize phosphorus to different oxidation states. **Hint:** Consider the oxidation states of phosphorus and how nitric acid can change these states during the reaction. ### Step 3: Products of the Reaction The reaction of white phosphorus with nitric acid primarily produces phosphoric acid (H3PO4) and nitrogen oxides (NO, NO2). The balanced reaction can be represented as follows: \[ P_4 + 10 HNO_3 \rightarrow 4 H_3PO_4 + 10 NO_2 + 2 H_2O \] **Hint:** Look for the common products formed when phosphorus reacts with nitric acid, especially focusing on the formation of phosphoric acid. ### Step 4: Conclusion Thus, the main products of the reaction between white phosphorus and nitric acid are phosphoric acid and nitrogen oxides. **Final Answer:** White phosphorus when reacts with nitric acid gives phosphoric acid (H3PO4) and nitrogen oxides (NO, NO2).
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Knowledge Check

  • White phosphorus reacts with chlorine and the product hydrolyses in the presence of water. Calcualte the mass of HCl obtained by the hydrolysis of the product formed by the reaction of 62 g of white phosphorus with chlorine in the presence of water.

    A
    200 g
    B
    400 g
    C
    219 g
    D
    100 g
  • White phosphorus reacts with caustic soda to form PH_(3) and NaH_(2) PO_(2) . This reaction is an example of

    A
    oxidation
    B
    reduction
    C
    disproportionation
    D
    displacement
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