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Describe the mechanism of alcohol reacti...

Describe the mechanism of alcohol reacting both as nucleophiles and electrophiles in reactions.

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Alcohols as nucleophiles :

Alcohols as electrophiles :
Protonated alcohols act as electrophiles
`R-CH_(2)-OH+H^(+)rarr R-CH_(2)-overset(+)OH_(2)`
`Br^(-)+underset(R)underset(|)CH_(2)-overset(+)OH_(2)rarr Br - underset(R)underset(|)CH_(2)+overset(+)H_(2)O`
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U-LIKE SERIES-ALCOHOLS, PHENOLS AND ETHERS-SHORT ANSWER QUESTIONS
  1. Explain the following giving one example for each : (i) Reimer - Tie...

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  2. Illustrate the following reactions giving a chemical equation for each...

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  3. Describe the mechanism of alcohol reacting both as nucleophiles and el...

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  4. Complete the following reaction equations :

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  5. Describe the mechanism of the formation of diethyl ether from ethanol ...

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  6. Give chemical tests to distinguish between compounds in each of the fo...

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  7. Why is the reactivity of all the three classes of alcohols with conc. ...

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  8. In Koble.s reaction, instead of phenol, phenoxide ion is treated with ...

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  9. Ethers can be prepared byWilliamson synthesis in which an alkyl halide...

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  10. Which is a stronger acid - phenol or cresol ? Explain.

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  11. Write steps to carry out the conversion of phenol to aspirin.

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  12. Nitration is an example of electrophilic substitution and its rate dep...

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  13. Dipole moment of phenol is smaller than that of methanol. Why?

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  14. How many the following conversions be carried out : (i) Propene to p...

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  15. Write one chemical reaction each to illustrate the following : (i) W...

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  16. What happens when ethanol is heated with conc. H(2)SO(4) at 453 K ? Ex...

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  17. Write the reaction and the conditions involved in the conversion of : ...

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  18. How are the following conversions carried out ? (a) Benzyl chloride...

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  19. Explain how an OH group attached to a carbon in the benzene ring activ...

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  20. How are the following conversions carried out? (i) Phenol to Toluene...

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