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One of the reaction that takes place in ...

One of the reaction that takes place in producing steel from iron ore is the reduction of iron (II) oxide by carbon monoxide to give iron metal and `CO_2`.
`FeO_((s))+CO_((g)) hArr Fe_((s)) + CO_(2(g)) K_p`=0.265 atm at 1050 K.
What are the equilibrium partial pressures of CO and `CO_2` at 1050 K if the initial partial pressures are: `p_(CO)` = 1.4 atm and `2p_(CO_2)`=0.80 atm ?

Text Solution

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`{:("Equillbrium reaction :", FeO_((s))+ CO_((g)) hArr , Fe_((s))+CO_(2(g))),("Initial partial pressure :", "1.4 atm","0.80 atm"),("Change in pressure :", "-x atm", "+x atm"),("Partial pressure at equilibrium:",(1.4-x),(0.80-x)):}`
where , x=1 pressure change in forward reaction.
`K_p=(p_(CO_2))/(p_(CO))`
`therefore 0.265=(0.80+x)/(1.4-x)`
`therefore` 0.265(1.4)-0.265x=0.80 +x
`therefore` 0.371 -0.80 =x + 0.265x
`therefore` 1.265x=-0.429
`therefore x=(-0.429)/1.265`=-0.3391 atm
So, `p_(CO)`=1.4 - (-0.3391)=1.7391
`p_(CO_2)`= 0.80+x =0.80-0.3391
=0.4609 = 0.461 atm
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