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An organic aromatic compound 'A' with th...

An organic aromatic compound 'A' with the molecular formula `C_(6)H_(7)N` is sparingly soluble in water. 'A' on treatment with dil. HCl gives a water soluble compound 'B'. 'A' also reacts with chloroform in presence of alcoholic KOH to form an obnoxious smelling compound 'C'. 'A' reacts with benzene sulphonyl chloride to form an alkali soluble compound 'D'. 'A' reacts with `NaNO_(2)` and HCl to form a compound 'E' which on reaction with phenol forms an orange red dye 'F'. Elucidate the structures of the organic compounds from 'A' to 'F'

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The structures of compounds A to F are given below :
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U-LIKE SERIES-AMINES-LONG ANSWER QUESTIONS-I (3 MARKS EACH)
  1. Give structures of A, B and C in the following reactions : (i) C(6)H...

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  2. Account for the following : (i) Primary amines (R-NH(2)) have higher...

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  3. Give the structures of A, B and C in the following reactions : (i) C...

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  4. State reasons for the following : (i) pK(b) value for aniline is mor...

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  5. (i) Explain why an alkylamine is more basic than ammonia. (ii) How w...

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  6. (a) Give one chemical test to distinguish between the following pairs ...

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  7. Giving an example of each, describe the following reactions : (i) H...

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  8. State the reactions and reactions conditions for the following convers...

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  9. Complete the following reaction equations : (i) Complete the followi...

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  10. (a) Give plausible explanation for each of the following : (i) The p...

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  11. (a) Give chemical tests to distinguish between the following compounds...

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  12. Account for the following observations : (i) PK(b) for aniline is mo...

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  13. An aromatic compound (A) on treatment with ammonia followed by heating...

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  14. State the reactions and reaction conditions for the following conversi...

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  15. (i) Stating the necessary reaction conditions write chemical reaction ...

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  16. Explain why the amino group in aniline acts as a powerful activator an...

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  17. How will you convert 4-nitrotoluene to 2-bromobenzoic acid ?

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  18. Two isomeric compounds A and B having molecular formula C(4)H(11)N, bo...

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  19. (i) Illustrate the following reactions : (a) Hoffmann bromamide degr...

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  20. An organic aromatic compound 'A' with the molecular formula C(6)H(7)N ...

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