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Which of the following orders is true re...

Which of the following orders is true regarding the acidic nature of phenol?

A

Phenol `gt` O-cresol `gt` O-nitrophenol

B

O-cresol `lt` phenol `lt` O-nitrophenol

C

phenol `lt` 0-cresol `gt` O-nitrophenol

D

phenol `lt` O-cresol `lt` O-nitrophenol III

Text Solution

Verified by Experts

The correct Answer is:
B

Presence of electron releasing group like CH3 over benzene nucleus destabilises the phenoxide ion, thus decreases the acidity of phenol where as Presence of electron withdrawing group like `NO_2` stabilises the phonoxide ion and thus increases acidity of Phenol, hence order of acidity will be O-cresol `lt` phenol `lt` O- nitrophenol
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