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Given that 10g of a dibasic acid (molar ...

Given that 10g of a dibasic acid (molar mass = 100) are present in 600 mL of the solution. The density of the solution is `1.02 g mL^(-1)`. Molality of solution is

A

0.17

B

0.34

C

0.99

D

0.01

Text Solution

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The correct Answer is:
To find the molality of the solution, we will follow these steps: ### Step 1: Calculate the number of moles of the dibasic acid. The formula for calculating the number of moles is: \[ \text{Number of moles} = \frac{\text{mass (g)}}{\text{molar mass (g/mol)}} \] Given: - Mass of dibasic acid = 10 g - Molar mass of dibasic acid = 100 g/mol \[ \text{Number of moles} = \frac{10 \text{ g}}{100 \text{ g/mol}} = 0.1 \text{ moles} \] ### Step 2: Calculate the mass of the solution. To find the mass of the solution, we can use the formula: \[ \text{Mass of solution} = \text{Volume} \times \text{Density} \] Given: - Volume of solution = 600 mL = 0.6 L (since 1 L = 1000 mL) - Density of solution = 1.02 g/mL Convert volume to grams: \[ \text{Mass of solution} = 600 \text{ mL} \times 1.02 \text{ g/mL} = 612 \text{ g} \] ### Step 3: Calculate the mass of the solvent. To find the mass of the solvent, we need to subtract the mass of the solute from the mass of the solution. \[ \text{Mass of solvent} = \text{Mass of solution} - \text{Mass of solute} \] Given: - Mass of solute (dibasic acid) = 10 g \[ \text{Mass of solvent} = 612 \text{ g} - 10 \text{ g} = 602 \text{ g} \] ### Step 4: Convert the mass of the solvent to kilograms. Since molality is defined as moles of solute per kilogram of solvent, we need to convert grams to kilograms. \[ \text{Mass of solvent in kg} = \frac{602 \text{ g}}{1000} = 0.602 \text{ kg} \] ### Step 5: Calculate the molality of the solution. The formula for molality (m) is: \[ \text{Molality (m)} = \frac{\text{Number of moles of solute}}{\text{Mass of solvent (kg)}} \] Substituting the values we have: \[ \text{Molality (m)} = \frac{0.1 \text{ moles}}{0.602 \text{ kg}} \approx 0.166 \text{ mol/kg} \] ### Conclusion Thus, the molality of the solution is approximately **0.166 mol/kg**. ---
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