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In HCI molecule, expected value of dipol...

In HCI molecule, expected value of dipole moment is 6.12 D but experimental value is 1.03 D. Then, the percentage ionic character will be

A

`16.13`

B

`15.14`

C

`6.02`

D

`18.9`

Text Solution

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The correct Answer is:
To calculate the percentage ionic character of HCl based on the given dipole moments, we can follow these steps: ### Step 1: Understand the formula for percentage ionic character The formula to calculate the percentage ionic character is given by: \[ \text{Percentage Ionic Character} = \left( \frac{\mu_{\text{observed}}}{\mu_{\text{calculated}}} \right) \times 100 \] Where: - \(\mu_{\text{observed}}\) is the experimental dipole moment. - \(\mu_{\text{calculated}}\) is the expected dipole moment. ### Step 2: Identify the values given in the question From the question, we have: - \(\mu_{\text{observed}} = 1.03 \, \text{D}\) (experimental value) - \(\mu_{\text{calculated}} = 6.12 \, \text{D}\) (expected value) ### Step 3: Substitute the values into the formula Now, we can substitute the values into the formula: \[ \text{Percentage Ionic Character} = \left( \frac{1.03 \, \text{D}}{6.12 \, \text{D}} \right) \times 100 \] ### Step 4: Perform the calculation First, calculate the fraction: \[ \frac{1.03}{6.12} \approx 0.168 \] Now, multiply by 100 to find the percentage: \[ 0.168 \times 100 \approx 16.8 \] ### Step 5: Final result Thus, the percentage ionic character of HCl is approximately: \[ \text{Percentage Ionic Character} \approx 16.8\% \]
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