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The strength of bonds formed by overlapp...

The strength of bonds formed by overlapping of `2s-2s`, `2p-2p` and `2p-2s` follows the order

A

`2s-2s gt 2p-2p gt 2s-2p`

B

`2s-2sgt 2p-2s gt 2p-2p`

C

`2p-2pgt2s-2pgt 2s-2s`

D

`2p-2p gt 2s-2s gt 2p-2s`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the strength of bonds formed by the overlapping of `2s-2s`, `2p-2p`, and `2p-2s` orbitals, we can analyze the nature of these overlaps step by step. ### Step-by-Step Solution: 1. **Identify the Types of Overlaps:** - We have three types of overlaps to consider: - `2s-2s` - `2p-2p` - `2p-2s` (which is the same as `2s-2p`) 2. **Understanding Orbital Shapes:** - The `s` orbital is spherical in shape, while the `p` orbital has a dumbbell shape. This difference in shape affects how effectively the orbitals can overlap. 3. **Evaluate Overlap Strength:** - **2p-2p Overlap:** - This overlap is considered the strongest because both orbitals are of the same type (p orbitals) and can align effectively to maximize overlap. - **2p-2s Overlap:** - The overlap between a p orbital and an s orbital is less effective than p-p overlap but more effective than s-s overlap. The p orbital can interact with the spherical s orbital, leading to a moderate bond strength. - **2s-2s Overlap:** - The overlap between two s orbitals is the weakest among the three types. While they can overlap, the spherical nature of the s orbitals does not allow for as effective a bond as the p orbitals. 4. **Order of Bond Strength:** - Based on the analysis above, we can establish the order of bond strength from strongest to weakest: - **2p-2p > 2p-2s > 2s-2s** 5. **Conclusion:** - Therefore, the strength of bonds formed by overlapping of `2s-2s`, `2p-2p`, and `2p-2s` follows the order: - **2p-2p > 2p-2s > 2s-2s** ### Final Answer: The order of bond strength is: **2p-2p > 2p-2s > 2s-2s**.
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