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the enol form of hept-5-en-2-one contain...

the enol form of `hept-5-en-2-`one contains

A

17sigma-bonds and 2π-bonds

B

19sigma-bonds and 2π-bonds

C

15sigma-bonds and 1π-bond

D

21sigma-bonds and 2π-bonds

Text Solution

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The correct Answer is:
To determine the enol form of hept-5-en-2-one, we will follow these steps: ### Step 1: Identify the Structure of Hept-5-en-2-one Hept-5-en-2-one has 7 carbon atoms (hept) and a double bond starting at the 5th carbon (5-en) with a ketone functional group at the 2nd carbon (2-one). The structure can be drawn as follows: ``` CH3-CH2-C(=O)-CH=CH-CH2-CH3 ``` ### Step 2: Draw the Enol Form To convert the ketone to its enol form, we need to perform a tautomerization reaction. This involves the migration of a hydrogen atom and the conversion of the carbonyl group (C=O) into an alcohol (C-OH) while forming a double bond between the adjacent carbon atoms. 1. Move one hydrogen from the 3rd carbon (C3) to the oxygen of the carbonyl group (C=O). 2. The double bond between C4 and C5 will shift to create a double bond between C2 and C3. The enol form can be represented as: ``` CH3-CH=C(OH)-CH=CH-CH2-CH3 ``` ### Step 3: Count Sigma and Pi Bonds Now, we will count the sigma (σ) and pi (π) bonds in the enol form. - **Sigma Bonds**: Each single bond counts as one sigma bond, and each double bond counts as one sigma bond plus one pi bond. - **Pi Bonds**: Each double bond counts as one pi bond. In the enol structure: - The sigma bonds can be counted as follows: - C1 to C2: 1 - C2 to C3: 1 - C3 to C4: 1 - C4 to C5: 1 - C5 to C6: 1 - C6 to C7: 1 - C1 to H: 3 (3 H atoms on C1) - C2 to H: 1 (1 H atom on C2) - C3 to H: 1 (1 H atom on C3) - C4 to H: 1 (1 H atom on C4) - C5 to H: 2 (2 H atoms on C5) - C6 to H: 2 (2 H atoms on C6) Total sigma bonds = 19 - **Pi Bonds**: There are 2 double bonds in the enol form. Total pi bonds = 2 ### Final Answer The enol form of hept-5-en-2-one contains **19 sigma bonds and 2 pi bonds**. ---
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