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The shape of CH3^(+) and CH3^(-) is resp...

The shape of `CH_3^(+) and CH_3^(-)` is respectively

A

plner,planer

B

plner,pyramidal

C

pyramidal,pyramidal

D

pyramidal,planer

Text Solution

AI Generated Solution

The correct Answer is:
To determine the shapes of the ions \( CH_3^+ \) (methyl cation) and \( CH_3^- \) (methyl anion), we need to analyze their hybridization and molecular geometry. ### Step-by-Step Solution: 1. **Identify the Hybridization of \( CH_3^+ \)**: - The methyl cation \( CH_3^+ \) has one less electron than neutral methane \( CH_4 \). - It has three hydrogen atoms and a positive charge, which means it has a total of 6 valence electrons (4 from carbon and 3 from hydrogen, minus 1 for the positive charge). - The carbon atom in \( CH_3^+ \) forms three sigma bonds with the hydrogen atoms and has no lone pairs. - Therefore, the hybridization is \( sp^2 \) because it uses three \( sp^2 \) hybrid orbitals to form these bonds. **Shape**: The geometry of \( sp^2 \) hybridized molecules is trigonal planar. 2. **Identify the Hybridization of \( CH_3^- \)**: - The methyl anion \( CH_3^- \) has one extra electron compared to neutral methane \( CH_4 \). - It has three hydrogen atoms and a negative charge, which means it has a total of 8 valence electrons (4 from carbon and 3 from hydrogen, plus 1 for the negative charge). - The carbon atom in \( CH_3^- \) forms three sigma bonds with the hydrogen atoms and has one lone pair. - Therefore, the hybridization is \( sp^3 \) because it uses four \( sp^3 \) hybrid orbitals (three for bonding and one for the lone pair). **Shape**: The geometry of \( sp^3 \) hybridized molecules is tetrahedral, but due to the presence of the lone pair, the shape is described as trigonal pyramidal. ### Final Answer: - The shape of \( CH_3^+ \) is **trigonal planar**. - The shape of \( CH_3^- \) is **trigonal pyramidal**.
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