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On treating sodium fusion extract with s...

On treating sodium fusion extract with sodium nitroprusside, a violet colour was observed. This indicates the presence of which element in the organic compound?

A

Nitrogen

B

Sulphur

C

Chlorine

D

Bromine

Text Solution

AI Generated Solution

The correct Answer is:
To determine which element is indicated by the violet color observed when treating a sodium fusion extract with sodium nitroprusside, we can follow these steps: ### Step 1: Understand the Sodium Fusion Test The sodium fusion test is a qualitative analysis method used to detect certain elements in organic compounds. When an organic compound is fused with sodium, it can release elements like sulfur, nitrogen, and halogens. **Hint:** Remember that sodium fusion helps to convert elements in the organic compound into their respective sodium salts. ### Step 2: Identify the Reaction with Sodium Nitroprusside Sodium nitroprusside is a reagent that can react with certain ions to produce a color change. Specifically, it is known to produce a violet or purple color in the presence of sulfide ions (S²⁻). **Hint:** Focus on the specific color changes associated with different ions when using sodium nitroprusside. ### Step 3: Analyze the Violet Color Observation The violet color observed indicates the presence of sulfide ions. When sodium fusion extract containing sulfur is treated with sodium nitroprusside, it forms a complex that exhibits a violet color. **Hint:** Consider what elements are known to produce a violet color when reacted with sodium nitroprusside. ### Step 4: Conclusion Since the violet color is specifically associated with the presence of sulfur in the organic compound, we conclude that the element indicated by the violet color is sulfur. **Final Answer:** The presence of sulfur in the organic compound is indicated by the violet color observed when treating the sodium fusion extract with sodium nitroprusside.
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Knowledge Check

  • In an alkaline solution, sodium nitroprusside gives a violet colour with :

    A
    `S^(2-)`
    B
    `SO_(3)^(2-)`
    C
    `SO_(4)^(2-)`
    D
    `NO_(3)^(-)`
  • Lassaigne's solution gives violet colouration with sodium nitroprusside. It indicates the presence of

    A
    nitrogen
    B
    sulphur
    C
    halogen
    D
    both N and S.
  • In Lassaigne's solution, pink/violet colouration is produced when sodium nitroprusside solution is added. It indicates the presence of:

    A
    sulphur
    B
    nitrogen
    C
    chlorine
    D
    none of these
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