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The following reaction takes place throu...

The following reaction takes place through `CH_3-O-CH_2-CH_3 + HI` to `CH_3-I + CH_3-CH_3-CH_2-OH`

A

`S_N1` mechanism

B

`S_N2` mechanism

C

`S_N1` in first step and E2 in second step

D

`S_N2` in first step and E1 in second step

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The correct Answer is:
To solve the problem involving the reaction of ether with HI, we can break down the process step by step. ### Step 1: Identify the Reactants The reactants in the reaction are: - Ether: \( CH_3-O-CH_2-CH_3 \) (ethyl methyl ether) - Hydroiodic acid: \( HI \) ### Step 2: Protonation of Ether When the ether reacts with HI, the ether oxygen atom gets protonated by the hydrogen ion (H⁺) from HI. This step forms a protonated ether intermediate, which is more reactive. **Reaction:** \[ CH_3-O-CH_2-CH_3 + H^+ \rightarrow CH_3-O^+-CH_2-CH_3 \] ### Step 3: Formation of Nucleophile The protonated ether is now a good leaving group. The bond between the oxygen and the ethyl group (CH₂-CH₃) can break, leading to the formation of a methyl cation and a nucleophile (iodide ion, I⁻) from HI. **Reaction:** \[ CH_3-O^+-CH_2-CH_3 \rightarrow CH_3^+ + CH_2-CH_3-OH \] ### Step 4: Nucleophilic Attack The iodide ion (I⁻) acts as a nucleophile and attacks the less hindered methyl cation (CH₃⁺). This is an SN2 reaction, which is favored due to the less steric hindrance around the methyl group. **Reaction:** \[ CH_3^+ + I^- \rightarrow CH_3-I \] ### Step 5: Final Products The final products of the reaction are: - Methyl iodide: \( CH_3-I \) - Ethanol: \( CH_3-CH_2-CH_2-OH \) **Overall Reaction:** \[ CH_3-O-CH_2-CH_3 + HI \rightarrow CH_3-I + CH_3-CH_2-CH_2-OH \] ### Conclusion The reaction proceeds through an SN2 mechanism, where the iodide ion attacks the methyl cation, leading to the formation of methyl iodide and ethanol. ---
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AAKASH INSTITUTE-MOCK TEST 37-Exercise
  1. Order of reactivity of hydrogen halides towards ethers is

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  2. The major product formed in the following reaction is (AAKMCP37NEETCHE...

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  3. The following reaction takes place through CH3-O-CH2-CH3 + HI to CH3-I...

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  4. Which of the following is a appropriate set of reactants for the prepa...

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  5. IUPAC nome of the following compound is (AAKMCP37NEETCHEE37005Q01)

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  6. The common name of Prop-2-enal is

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  7. For denaturation of ethanol

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  8. In aldehydes and ketones

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  9. The correct structure of the product of the following reaction will be...

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  10. Identify the major product obtained when anisole reacts with bromine i...

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  11. Major product formed in the following reaction is (AAKMCP37NEETCHEE370...

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  12. Reaction of (AAKMCP37NEETCHEE37012Q01)with HI (one mole) leads to the ...

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  13. In the following reaction: (AAKMCP37NEETCHEE37013Q01) The major produc...

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  14. Major product obtained in the reaction is (AAKMCP37NEETCHEE37014Q01)

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  15. Consider the following sequence of reaction: (AAKMCP37NEETCHEE37015Q01...

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  16. Which of the following compound(s) will give glyoxal as one of the pro...

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  17. Addition of water to ethyne in the presence of H2SO4 and HgSO4 gives

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  18. The given reaction is an example of (AAKMCP37NEETCHEE37018Q01)

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  19. Product obtained in the reaction (AAKMCP37NEETCHEE37019Q01)

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  20. The correct name and product of given reaction are respectively (AAKMC...

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