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If f denotes the degree of freedom of a ...

If f denotes the degree of freedom of a gas, the ratio of two specific heats `(C_(P))/(C_(V))` is given by

A

`(1)/(f)+1`

B

`(2)/(f)+1`

C

`(1)/(f)-1`

D

`(2)/(f)-1`

Text Solution

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The correct Answer is:
To find the ratio of the specific heats \( \frac{C_P}{C_V} \) in terms of the degrees of freedom \( F \) of a gas, we can follow these steps: ### Step 1: Understand the Degrees of Freedom The degrees of freedom \( F \) of a gas refers to the number of independent ways in which the gas molecules can move. For a monoatomic gas, \( F = 3 \) (translational motion), for a diatomic gas, \( F = 5 \) (3 translational + 2 rotational), and for more complex molecules, \( F \) can be higher. ### Step 2: Use the Equipartition Theorem According to the equipartition theorem, the internal energy \( U \) of a gas is related to its degrees of freedom. The total internal energy can be expressed as: \[ U = \frac{F}{2} nRT \] where \( n \) is the number of moles, \( R \) is the universal gas constant, and \( T \) is the temperature. ### Step 3: Relate Internal Energy to Heat Capacities The heat capacity at constant volume \( C_V \) is defined as: \[ C_V = \frac{dU}{dT} \] From the expression for internal energy, we can differentiate with respect to temperature: \[ C_V = \frac{d}{dT}\left(\frac{F}{2} nRT\right) = \frac{F}{2} nR \] ### Step 4: Use the Relation between \( C_P \) and \( C_V \) For an ideal gas, the relationship between the heat capacities is given by: \[ C_P - C_V = R \] Substituting the expression for \( C_V \): \[ C_P - \frac{F}{2} nR = R \] This can be rearranged to find \( C_P \): \[ C_P = \frac{F}{2} nR + R = \left(\frac{F}{2} + 1\right) nR \] ### Step 5: Find the Ratio \( \frac{C_P}{C_V} \) Now we can find the ratio of the specific heats: \[ \frac{C_P}{C_V} = \frac{\left(\frac{F}{2} + 1\right) nR}{\frac{F}{2} nR} \] This simplifies to: \[ \frac{C_P}{C_V} = \frac{\frac{F}{2} + 1}{\frac{F}{2}} = 1 + \frac{2}{F} \] ### Final Result Thus, the ratio of the specific heats \( \frac{C_P}{C_V} \) is given by: \[ \frac{C_P}{C_V} = 1 + \frac{2}{F} \]

To find the ratio of the specific heats \( \frac{C_P}{C_V} \) in terms of the degrees of freedom \( F \) of a gas, we can follow these steps: ### Step 1: Understand the Degrees of Freedom The degrees of freedom \( F \) of a gas refers to the number of independent ways in which the gas molecules can move. For a monoatomic gas, \( F = 3 \) (translational motion), for a diatomic gas, \( F = 5 \) (3 translational + 2 rotational), and for more complex molecules, \( F \) can be higher. ### Step 2: Use the Equipartition Theorem According to the equipartition theorem, the internal energy \( U \) of a gas is related to its degrees of freedom. The total internal energy can be expressed as: \[ ...
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