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During monoalkylation of Benzene with CH...

During monoalkylation of Benzene with `CH_3Cl` in presence of anhydrous `AlCl_3`, an excess of `C_6H_6` must be used because this will.

A

Increase the chance for collision between `CH_3^(+) and C_6H_6`

B

Decrease the collision betweeen `CH_3^(oplus) and C_6H_5CH_3`

C

both a and b

D

Decrease the chance for collision between `CH_3^(oplus) and C_6H_6`

Text Solution

Verified by Experts

The correct Answer is:
C

Since `CH_3` group is an activating group , the mono methylated product is more reactive than benzene itself leading to formation of `C_6H_4(CH_3)_2 and C_6H_3(CH_3)_3`. Excess of `C_6H_6` is used to increase the chance for collision between and to minimize collision between `CH_2^(oplus) and C_6H_5CH_3`.
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AAKASH SERIES-HYDROCARBONS-ADDITIONAL PRACTICE SHEET ( LEVEL-I (LECTURE SHEET (MAIN) (STRAIGHT OBJECTIVE TYPE QUESTIONS)))
  1. Which the following reagent can not form tert- pentyl Benzene as the m...

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  2. C6H6 + C6H5Cl overset(AlCl3)to P , P is

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  3. During monoalkylation of Benzene with CH3Cl in presence of anhydrous A...

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  4. ter-Butyl benzene can be obtained by

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  5. Which of the following statement is true.

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  6. Which of the following structure is least stable?

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  7. Which of the following is comparatively stable?

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  8. Which of the following is not an example of friedel-craft reaction.

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  9. When carbon tetrachloride is treated with excess of Benzene in presenc...

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  10. Which of the following statement is true?

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  11. What happens when aniline is treated with methyl chloride in presence ...

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  12. Which of the following is a nonaromatic.

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  13. Which of the following structures are aromatic

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  14. Purine has four nitrogen atoms, which one of them is expected to be ba...

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  15. C6H6 +CH2Cl2 overset(AlCl3)to C , excess .

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  16. The correct order of increasing basic nature for the following compoun...

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  17. The increasing order of the acidic nature of the following compounds i...

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  18. In Huckel's (4n+2) rule of for aromaticity, 'n' represents

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  19. Which of the following are conjugated dienes?

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  20. What is the correct order of exothermicity for hydrogenation of the fo...

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