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Explain hydrate isomerism. Give some exa...

Explain hydrate isomerism. Give some examples.

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This isomerism is due to different role of water molecule present in the complex compound. Water molecule can either act as ligand or it may present outside the coordination sphere as anion water. Example:(i)`[Co(NH_3)_3(H_2O)_2CI]Br_2` and `[Co(NH_3)_3(H_2O)Cibber]BrH_2O` (ii) `[Co(NH_3)_4(H_2O)CI]Br_2` and `[Co(NH_3)_4Br]CI.H_2O`
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MBD PUBLICATION-COORDINATION COMPOUNDS-QUESTION BANK
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  2. How coordination compounds are used in analytical chemistry ?

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  3. Explain hydrate isomerism. Give some examples.

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  4. Distinguish between double salt and complex salt

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  5. What are the different types of complexes ?

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  6. What are the primary valencies ?

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  7. What are the secondary valencies ?

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  8. What are the drawbacks of Werner’s co-ordination theory ?

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  9. What is functional isomerism ? Give one example.

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  10. What is Werner’s coordination theory ?

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  11. What is isomerism ? Discuss structural isomerism in coordination compo...

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  12. Explain geometrical isomerism in coordination compounds having coordin...

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  13. What is optical isomerism in coordination compounds ? Explain with exa...

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  14. Write various postulates and applications of valence bond theory in co...

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  15. Give main features of crystal field theory of coordination compounds i...

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  16. Discuss colour in coordination compounds.

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  17. Describe limitations of crystal field theory.

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  18. Explain bonding in metal carbonyls.

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  19. Discuss various applications of coordination compounds.

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