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Which is low spin complex:...

Which is low spin complex:

A

`Fe(CN)_6^(3-)`

B

`Co(NO_2)_6^(3-)`

C

`Mn(CN)_6^(3-)`

D

All

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The correct Answer is:
A
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Between [Fe(H_2O)_6]^(3+) and [Fe(CN)_6]^(3-) which is a low spin complex and why ?

Which is high spin complex:

Square planar complexes of MX_(2)L_(2) type with coordination number of 4 exhibit geometrical isomerism whereas tetrahedral complexes with similar composition do not. Why? Justify the formation of a low spin complex and a high spin complex taking the examples of [Fe(CN)_(6)]^(3-) and [FeF_(6)]^(3-) on the bases of "crystal field splitting energy". (Delta_(0))

MBD PUBLICATION-COORDINATION COMPOUNDS-QUESTION BANK
  1. Complexes with CN^- ligands are usually:

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  2. The effective atomic number rule is less likely to apply if the metal-...

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  3. Which is low spin complex:

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  4. Which exhibits highest molar conductivity:

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  5. Which ligand is capable of forming low spin well as high spin complexe...

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  6. The tetrahedral crystal field splitting is only of the octahedral spli...

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  7. Which order is correct in spectrochemical series of ligands:

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  8. Which is high spin complex:

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  9. A complex shown helow can be exhibit:

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  10. Silver dissolves in the solution of an alkali cyanide in the presence ...

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  11. Which ion is paramagnetic:

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  12. Point out the central ion ligand in the complex K2[Cd(CN)4].

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  13. Which one of the following does not give a white precipitate with silv...

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  14. in solid CuSO4 .5H2O copper is co-ordinated to:

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  15. CuCl is sparingly soluble in H2O but it dissolves in KCI solution due ...

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  16. The co-ordination number of copper in the complex formed by adding exc...

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  17. The coordination number of central metal ion in [Cu(H2O)4]^(2+) is:

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  18. Magnetic moment of [Ag(CN)2]^ is zero. How many unpaired electrons are...

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  19. CuSO4 reacts with KCN solution forming a complex. Co-ordination number...

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  20. The unpaired electrons in [Ni(CO)4] are:

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