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Which of the following alkyl halides is ...

Which of the following alkyl halides is not suitable for Corey-House synthesis of alkanes?

A

`CH_3Br`

B

`C_2H_5I`

C

`CH_3CH_2CH_2I`

D

`(CH_3)_3CBr`

Text Solution

Verified by Experts

The correct Answer is:
D

Reactivity of alkyl halides towards Gilman reagent (`R_2CuLi`) decreases in the order. i.e., `1^(@) gt 2^(@) gt 3^(@)`
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