Home
Class 11
CHEMISTRY
Oxymercuration demercuration reacti on i...

Oxymercuration demercuration reacti on is process of addition `H_2O` according to Markownikoff's rule without any rearrangement .
`CH_3 - CH = CH_2 underset(NaBH_4. overset(odot)OH)overset(Hg(OAc)_2 . H_2O) to CH_3 - underset(OH)underset(|)CH=CH_3`
Mechanism :
`Hg(OAc)_2 iffoverset(oplus)Hg(OAc) + Acoverset(odot)O`

Base `overset(Ɵ)OH` is used to neutralise `H^(oplus)` produced during the reaction :

A

B

C

D

both (1) and (2)

Text Solution

Verified by Experts

The correct Answer is:
B

Promotional Banner

Similar Questions

Explore conceptually related problems

CH_3 - overset(CH_3)overset(|)C = CH-CH_3 overset(Hg(OAc)_2 // EtOH)to underset((90%))((A)) .

Hydroboration oxidation reaction is process of addition of H_2O according to antimarkownikoff's rule. CH_3CH = CH_2 underset(H_2O_2, overset(Ɵ)OH)overset(BH_3,THH)to CH_3 - CH_2 - CH_2 OH Reaction is regioselective. Regioselectivity of reaction is increased by using hindered boranes. THF (Tetrahydrofuran) is used to control reactivity of borane. Major product

Hydroboration oxidation reaction is process of addition of H_2O according to antimarkownikoff's rule. CH_3CH = CH_2 underset(H_2O_2, overset(Ɵ)OH)overset(BH_3,THH)to CH_3 - CH_2 - CH_2 OH Reaction is regioselective. Regioselectivity of reaction is increased by using hindered boranes. THF (Tetrahydrofuran) is used to control reactivity of borane. Major product

IUPAC name of compound CH_(3)-underset(OH)underset(|)(CH)-overset(NH_(2))overset(|)(CH)-underset(CH_3)underset(|)(CH)-OH is

Hydroboration oxidation reaction is process of addition of H_2O according to antimarkownikoff's rule. CH_3CH = CH_2 underset(H_2O_2, overset(Ɵ)OH)overset(BH_3,THH)to CH_3 - CH_2 - CH_2 OH Reaction is regioselective. Regioselectivity of reaction is increased by using hindered boranes. THF (Tetrahydrofuran) is used to control reactivity of borane.

CH_3 - CH_2-CH_2 -C -= CH underset(THF)overset(BH_3)to underset(OH^(-))overset(H_2O_2)to Identify the product

H_3C -underset(CH_3)underset(|) overset(CH_3)overset(|)C-H+ C Cl_4 underset(hv)overset(R_2O_2)to " Product" :

CH_3 - overset(Cl)overset(|) CH -CH_3 overset(Alc.KOH)to CH_3 -CH =CH_2 underset(2 . H_2 O_2 // OH^(-))overset(1. BH_3)to CH_3 - CH_2 - overset(OH) overset(|)CH_2

Name the CH_(3)-CH_(2)-underset(CH_(2)Cl)underset(|)CH-overset(CH_(2)OH)overset(|)CH-underset(CH_(3))underset(|)CH-CH_(3) compound according to IUPAC system.

CH_3 -CH_2 -underset( O) underset(||) C - CHO overset( NaBH_4) to Product (s) in the above reaction is (are)