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In which of the following cases enol con...

In which of the following cases enol content will be higher than the keto content in n-hexane?

A

`CH_3-overset(O)overset(||)C-overset(O)overset(||)C-CH_3`

B

C

D

Text Solution

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The correct Answer is:
B, C

less repulsion between two `underset(C )overset(O)(||)` bonds . More repulsion C - C bond rotations not possible and two `underset(C)overset(O)(||)` are more stable than `underset(C)overset(O)(||)` and C = C bond. Repulsion minimised and stabilized by H - bonding

dve methylene group is present in between two strong electron with drawing groups.
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