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The chirality of the compounds H(3)C=ove...

The chirality of the compounds `H_(3)C=overset(Br)overset(|)underset(Cl)underset(|)C-H` is

A

R

B

S

C

E

D

Z

Text Solution

Verified by Experts

The correct Answer is:
B


According to CIP rules configurations is (S)
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In the given reaction sequence, CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)C-CH_(2)CH_(2)OH overset(K_(2)Cr_(2)O_(7),H_(2)SO_(4))underset(H_(2)O,Delta)to(A)overset(SOCl_(2))to(B)overset((CH_(3))_(2)NH)underset("mole")to(C)overset(1.LiAlH_(4))underset(2.H_(2)O)to(D)

Write the name of the organic compound which have the following structure. CH_2=overset(Cl)overset(|)CHunderset(Cl)underset(|)overset(CH_3)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-CH_3

Assign R or S configuration on the compound: H_(2)N-underset(CH_(3))underset(|)overset(COOH)overset(|)C-H

The monomer of the polymer [-CH_(2)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(2)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(2)-]_(n)

The IUPAC name of CH_(3)-underset(Br)underset(|)CH-underset(Cl)underset(|)CH_(2)overset(CH_(3))overset("| ")(-HC_() CH_(3)) is

The IUPAC name of the given compound CH_3-underset(Br)underset(|)(CH)-overset(CHO)overset(|)(CH)-overset(CONH_2)overset(|)(CH)-underset(COCl)underset(|)(CH)-COOH

The IUPAC name of CH_(3)-CH_(2)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")("C ")-underset(C_(2)H_(5))underset("| ")("C ")=CH-CH_(3)

CH_2 = CH - CH = underset(CH_3)underset(|)C-CH_3 overset(+HBr)to CH_3-overset(Br)overset(|)CH-CH = underset(CH_3)underset(|)C-CH_3 + underset((II))(CH_3 - CH ) = CH - underset(CH_3)underset(|)overset(Br)overset(|)C-CH_3 Correct statement about the above reaction is

Write the IUPAC name of the CH_(3)-underset(CH_(3))underset(|)CH-underset(OH)underset(|)CH-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(3) compound.

The IUPAC name of the compound is Cl - underset(underset(F)(|))overset(overset(Br)(|))(C )- CHO is

AAKASH SERIES-ISOMERISM -ADDITIONAL PRACTICE EXERCISE (LEVEL-I(MAIN) STRAIGHT OBJECTIVE TYPE QUESTIONS)
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  12. is

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