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(A) CrO3, reacts with HCl to form chromy...

(A) `CrO_3`, reacts with HCl to form chromyl chloride gas
(R) Chromyl chloride `(CrO_2Cl_2)` has tetra hedral shape

A

Both (A) and (R) are true and (R) is the correct explanation of (A)

B

Both (A) and (R) are true and (R) is not the correct explanation of (A)

C

(A) is true but (R) is false

D

Both (A) and (R) are false

Text Solution

Verified by Experts

The correct Answer is:
B
Both (A) and (R) are true and (R) is not the correct explanation of (A)
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K_2Cr_2O_7 acts as a good oxidizing agent in acidic medium underset("Orange")(Cr_(2)O_(7)^(2-)) + 14H^(+) + 6e^(-) rarr underset("Green")(2Cr^(3+)) + 7H_2O In alkaline solution, orange colour of Cr_(2)O_(7)^(2-) chages to yellow colour due to formation of Cr_2O_(4)^(2-) and again yellow colour changes to orange colour on changing the solution to acidic medium underset("Orange")(Cr_2O_7^(2-))+2OH^(_) rarrunderset("Yellow")(Cr_2O_7^(2-))+H_2O underset("Yellow")(2CrO_(4)^(2_-)) + 2H^(+) rarr underset("Orange")(Cr_(2)O_(7)^(2-) + H_(2)O) Cr_(4)^(2-) and Cr_(2)O_(7)^(2-) exist in equilibrium at pH =4 and are interconvertible by altering the pH of the solution. When heated with H_2SO_4 and metal chloride K_2Cr_2O_7 gives vapour of chromyl chloride (CrO_2Cl_2) . Chromyl chloride (CrO_2Cl_2) when passed into aqueous NaOH solution, yellow colour solution of CrO_(4)^(2-) is obtained. This on reaction with lead acetate gives yellow ppt. PbCrO_4 . When H_2O_2 is added to an acidified solution of dichromate ion, a complicated reaction occurs. The products obtained depend on the pH and concentration of dichromate. Cr_2O_7^(2-)+2H^(+) + 4H_(2)O_(2) rarr 2Cr(O_2)+5H_2O A deep blue-violet coloured peroxo compound, CrO(O_2)_2, ' called chromic peroxide is formed. This decomposes rapidly in aqueous solution into Cr^(3+) and xygen. CrO_3 on reaction with HCl and the product on reaction with NaOH(aq) give respectively

K_2Cr_2O_7 acts as a good oxidizing agent in acidic medium underset("Orange")(Cr_(2)O_(7)^(2-)) + 14H^(+) + 6e^(-) rarr underset("Green")(2Cr^(3+)) + 7H_2O In alkaline solution, orange colour of Cr_(2)O_(7)^(2-) chages to yellow colour due to formation of Cr_2O_(4)^(2-) and again yellow colour changes to orange colour on changing the solution to acidic medium underset("Orange")(Cr_2O_7^(2-))+2OH^(_) rarrunderset("Yellow")(Cr_2O_7^(2-))+H_2O underset("Yellow")(2CrO_(4)^(2_-)) + 2H^(+) rarr underset("Orange")(Cr_(2)O_(7)^(2-) + H_(2)O) Cr_(4)^(2-) and Cr_(2)O_(7)^(2-) exist in equilibrium at pH =4 and are interconvertible by altering the pH of the solution. When heated with H_2SO_4 and metal chloride K_2Cr_2O_7 gives vapour of chromyl chloride (CrO_2Cl_2) . Chromyl chloride (CrO_2Cl_2) when passed into aqueous NaOH solution, yellow colour solution of CrO_(4)^(2-) is obtained. This on reaction with lead acetate gives yellow ppt. PbCrO_4 . When H_2O_2 is added to an acidified solution of dichromate ion, a complicated reaction occurs. The products obtained depend on the pH and concentration of dichromate. Cr_2O_7^(2-)+2H^(+) + 4H_(2)O_(2) rarr 2Cr(O_2)+5H_2O A deep blue-violet coloured peroxo compound, CrO(O_2)_2, ' called chromic peroxide is formed. This decomposes rapidly in aqueous solution into Cr^(3+) and xygen. Which of the following statements is wrong when a mixture of NaCI and K_2Cr_2O_2 is gently walmed with conc. H_2SO_4 ?

K_2Cr_2O_7 acts as a good oxidizing agent in acidic medium underset("Orange")(Cr_(2)O_(7)^(2-)) + 14H^(+) + 6e^(-) rarr underset("Green")(2Cr^(3+)) + 7H_2O In alkaline solution, orange colour of Cr_(2)O_(7)^(2-) chages to yellow colour due to formation of Cr_2O_(4)^(2-) and again yellow colour changes to orange colour on changing the solution to acidic medium underset("Orange")(Cr_2O_7^(2-))+2OH^(_) rarrunderset("Yellow")(Cr_2O_7^(2-))+H_2O underset("Yellow")(2CrO_(4)^(2_-)) + 2H^(+) rarr underset("Orange")(Cr_(2)O_(7)^(2-) + H_(2)O) Cr_(4)^(2-) and Cr_(2)O_(7)^(2-) exist in equilibrium at pH =4 and are interconvertible by altering the pH of the solution. When heated with H_2SO_4 and metal chloride K_2Cr_2O_7 gives vapour of chromyl chloride (CrO_2Cl_2) . Chromyl chloride (CrO_2Cl_2) when passed into aqueous NaOH solution, yellow colour solution of CrO_(4)^(2-) is obtained. This on reaction with lead acetate gives yellow ppt. PbCrO_4 . When H_2O_2 is added to an acidified solution of dichromate ion, a complicated reaction occurs. The products obtained depend on the pH and concentration of dichromate. Cr_2O_7^(2-)+2H^(+) + 4H_(2)O_(2) rarr 2Cr(O_2)+5H_2O A deep blue-violet coloured peroxo compound, CrO(O_2)_2, ' called chromic peroxide is formed. This decomposes rapidly in aqueous solution into Cr^(3+) and xygen. What happens when a solution of potassium chromate is treated with an excess of dilute nitric acid?

When HCl reacts with finely powdered iron, it forms ferrous chloride and not ferric chloride. Why ?

When Cl_2 reacts with Fe (or) Cu it does not form

When HCl reacts with powdered iron, ferrous chloride is formed, but not ferric chloride. Why?

AAKASH SERIES-D-BLOCK ELEMENTS-OBJECTIVE EXERCISE-4 (ASSERTION (A) & REASON (R) TYPE QUESTIONS )
  1. (A): K(2)CrO(4) has yellow colour due to charge transfer (R) : CrO(4...

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  2. (A) The highest oxidation state of chromium in its compounds is + 6 ...

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  3. (A) CrO3, reacts with HCl to form chromyl chloride gas (R) Chromyl c...

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  4. (A) Tungsten has a very low melting point (R) Tungsten is a covalent...

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  5. (A) Cu^+ ion is coloured in aqueous solutions (R) Four water molecul...

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  6. (A) Equivalent mass of KMnO4 is equal to one-third of its molecular ma...

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  7. (A) Ce^(4+) is used as an oxidising agent in volumetric analysis. (R...

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  8. (A) In MnO(4)^(-) the M-O bonds are ionic . (R) The oxidation number ...

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  9. (A) Mn atom loses ns electrons first during ionization as compared to ...

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  10. (A) Aqueous solution of FeCl3 is acidic due to cationic hydrolysis ...

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  11. (A) Mercury is liquid at room temperature (R) In mercury, there is ...

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  12. (A) The purple colour of KMnO4 is due to the charge transfer transitio...

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  13. (A) The highest oxidation state of Os is +8. (R) Osmium is a 5d elem...

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  14. (A) Atomic size of silver is almost equal to that of gold. (R) d sub...

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  15. (A) Cr^(+2) is strong reducing agent in aqueous solution. (R) Cr^(+2...

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  16. (A) Potassium dichromate is used as a primary standard in volumetric a...

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  17. (A) Potassium ferrocyanide and potassium ferricyanide both are paramag...

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  18. (A) Zn^(+2) is diamagnetic (R) The electrons are lost from 4s orbita...

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  19. (A) d block elements are transitioned between s-block metals and p-blo...

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  20. (A) E.C of Pd is [Kr] 4d^(8)5s^(2) (R) Palladium contains 8e^(-) in ...

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