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Using the Rydberg formula, calculate the...

Using the Rydberg formula, calculate the wavelengths of the first four spectral lines in the Lyman series of the hydrogen spectrum.

Text Solution

Verified by Experts

From Rydberg formula,
`(h_(c))/(lambda_(if))=(me^(4))/(8 epsi_(0)^(2)h^(2))[(1)/(n_(f)^(2))-(1)/(n_(f)^(2))]=21.76xx10^(-19)[(n_(i)^(2)-1)/(m_(f)^(2))]`
`:. lambda_(if)=(h_(c))/(21.76xx10^(-19))[(n_(i)^(2))/(n_(i)^(2)-1)]`
`:. Lambda_(if)=(6.625xx10^(-34)xx3xx10^(8))/(21.76xx10^(-19))xx[(n_(i)^(2))/(n_(i)^(2)-1)]`
`:. lambda_(if)=(n_(i)^(2)xx913.4xx10^(-10)m)/(n_(i)^(2)-1)....(1)`
`rArr` Now putting `n_(i)=2` in equation, (1), we get the wavelenght of `alpha`- line of Lyman series.
`:. lambda_(21)=((2)^(2)xx913.4xx10^(-10))/((2)^(2)-1)`
`=(4xx913.4xx10^(-10))/(3)`
`=1217.8xx10^(-10)m=1218Å`
`rArr` Putting `n_(i)=3` in equation (1), the wavelength of `beta`- line of Lyman series,
`:. lambda_(31)=((3)^(2)xx931.4xx10^(-10))/((3)^(2)-1)`
`:. lambda_(31)=(9xx931.4xx10^(-10))/(8)`
`:. lambda_(31)=1027.5xx10^(-10)m=1028Å`
`rArr` Putting `n_(i)=4` in equation (1), the wavelength of `gamma`- line of Lyman series,
`:. lambda_(41)=((4)^(2)931.4xx10^(-10))/((4)^(2)-1)`
`=(16xx913.4xx10^(-10))/(15)`
`:. lambda_(41)=674.29xx10^(-10)m=974.3Å`
`rArr` Putting `n_(i)=5` in equation (1), the wavelength of `delta`- line of Lyman series
`:. lambda_(51)=((5)^(2)931.4xx10^(-10))/((5)^(2)-1)`
`=(25xx913.4xx10^(-10))/(24)`
`:. lambda_(51)= 951.45xx10^(-10)m=951.4Å`
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