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The wavelength of first line of Balmer s...

The wavelength of first line of Balmer series in hydrogen atom is 2, the wavelength of first of corresponding double ionized lithium atom is …………

A

`(lamda)/(3)`

B

`(lamda)/(4)`

C

`(lamda)/(9)`

D

`(lamda)/(27)`

Text Solution

Verified by Experts

The correct Answer is:
C

`(1)/(lamda)=Z^(2)R[(1)/(n_(f)^(2))-(1)/(n_(i)^(2))]`
Here for first line in Balmer series of hydrogen atom
`(1)/(lamda_(H))=Z_(H)^(2)R[(1)/(n_(f)^(2))-(1)/(3^(2))]`
For `L_(i),(1)/(lamda_(Li))=Z_(Li)^(2)R[(1)/(2^(2))-(1)/(3^(2))]`
`:.(lamda_(Li))/(lamda_(H))=(Z_(H)^(2))/(Z_(Li)^(2))=(1)/(9)" "(Z_(Li)=3,Z_(H)=1)`
`:.lamda_(Li)=(lamda_(H))/(9)` but `lamda_(H)=lamda:.lamda_(Li)=(lamda)/(9)`
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