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Molecular weights of ammonia and nitroge...

Molecular weights of ammonia and nitrogen are respectively `X_(1) and X_(2)`. In the reaction of producing ammonia.`N_(2)+3H_(2)to2NH_(3)` , the equivalent weights of ammonia and nitrogen are given as respectively `y_(1) and y_(2)`. Then how is `(y_(1)-y_(2))` related to molecular weights?

Text Solution

Verified by Experts

The correct Answer is:
`(2"x"_(2)-"x"_(1))//6)`
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The equivalent weights of oxidising and reducing agents can be calculated by the number of electrons gained or lost. The equivalent weight of an oxidising agent is the number of parts by weight of the substance which gains one electron. Thus, it is equal to the molecular weight of the substance divided by the number of electrons gained in the balanced chemical equation. Similarly, equivalent weight of a reducing agent is equal to the molecular weight divided by the number of electrons lost as represented in the balanced chemical equation The equivalent weght of As_(2),S_3 in the following reaction As_(2)S_(3) + H^(+) + NO_(3)^(-) rarr NO + H_(2)O + AsO_(4)^(3-) + SO_(4)^(2-) is related to its molecular weight as