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112% labelled oleum is diluted with suff...

112% labelled oleum is diluted with sufficient water. The solution on mixing with `5.3xx102gm Na_(2)CO_(3)` liberates `CO_(2)`. The volume of `Co_(2)` given out at 1 atm at 273 K will be

A

1.12 lit

B

1.23 lit

C

2.2 lit

D

25.5 lit

Text Solution

Verified by Experts

The correct Answer is:
D

Final weight of `H_(2)SO_(4)=112` gms
`Na_(2)O_(3)+H_(2)SO_(4)rarrNa_(2)SO_(4)+H_(2)O+CO_(2)`
530 gm 112 gm
= 5 moles 1.14 moles
implies volume of `CO_(2)=1.14xx22.4=25.5` lit.
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