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For a moles of gas ,Van der Weals equat...

For a moles of gas ,Van der Weals equation is `(p = (a)/(V^(-2))) (V - b) = nRT`ltbr. Find the dimensions of a `a and b `, where `p = pressure` of gas` ,V = volume` of gas and` T = temperature of gas` .

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To find the dimensions of \( a \) and \( b \) in the Van der Waals equation, we will analyze the equation step by step. ### Step 1: Understand the Van der Waals Equation The Van der Waals equation can be expressed as: \[ p = \frac{a}{V^2}(V - b) = nRT \] Where: - \( p \) = pressure - \( V \) = volume - \( T \) = temperature - \( n \) = number of moles - \( a \) and \( b \) are constants. ### Step 2: Identify the Dimensions of Each Variable 1. **Pressure \( p \)**: - Pressure is defined as force per unit area. - Dimensions of force = mass × acceleration = \( [M][L][T^{-2}] \) - Area = \( [L^2] \) - Therefore, dimensions of pressure \( p \) are: \[ [p] = \frac{[M][L][T^{-2}]}{[L^2]} = [M][L^{-1}][T^{-2}] \] 2. **Volume \( V \)**: - Volume is defined as length cubed. - Therefore, dimensions of volume \( V \) are: \[ [V] = [L^3] \] 3. **Temperature \( T \)**: - The dimension of temperature is denoted as: \[ [T] = [\Theta] \quad (\text{where } \Theta \text{ is the dimension of temperature}) \] ### Step 3: Find the Dimensions of \( b \) - From the equation \( V - b \), since both \( V \) and \( b \) are in the same term, they must have the same dimensions. - Therefore, the dimensions of \( b \) are: \[ [b] = [V] = [L^3] \] ### Step 4: Find the Dimensions of \( a \) - Rearranging the Van der Waals equation gives us: \[ p = \frac{a}{V^2} \implies a = p \cdot V^2 \] - Now substituting the dimensions: \[ [a] = [p] \cdot [V^2] = [M][L^{-1}][T^{-2}] \cdot [L^6] = [M][L^{5}][T^{-2}] \] ### Final Dimensions - The dimensions of \( a \) are: \[ [a] = [M][L^5][T^{-2}] \] - The dimensions of \( b \) are: \[ [b] = [L^3] \] ### Summary - Dimensions of \( a \): \( [M][L^5][T^{-2}] \) - Dimensions of \( b \): \( [L^3] \)

To find the dimensions of \( a \) and \( b \) in the Van der Waals equation, we will analyze the equation step by step. ### Step 1: Understand the Van der Waals Equation The Van der Waals equation can be expressed as: \[ p = \frac{a}{V^2}(V - b) = nRT \] Where: ...
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