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An ideal gas is taken through a process ...

An ideal gas is taken through a process in which the pressure and the volume are changed according to the equation `p=kv`. Show that the molar heat capacity of the gas for the process is given by `(C=C_v + ( R)/(2))`.

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To solve the problem, we need to derive the expression for the molar heat capacity \( C \) of an ideal gas undergoing a process defined by the equation \( p = kV \). Here’s a step-by-step solution: ### Step 1: Start with the Ideal Gas Law The ideal gas law is given by: \[ PV = nRT \] For one mole of gas (\( n = 1 \)), this simplifies to: \[ PV = RT \] ### Step 2: Substitute the given relationship \( p = kV \) From the problem, we have: \[ p = kV \] Substituting this into the ideal gas law gives: \[ (kV)V = RT \] This simplifies to: \[ kV^2 = RT \] ### Step 3: Differentiate with respect to \( T \) We differentiate both sides of the equation \( kV^2 = RT \) with respect to \( T \): \[ \frac{d}{dT}(kV^2) = \frac{d}{dT}(RT) \] Using the product rule on the left side, we get: \[ k \cdot 2V \frac{dV}{dT} = R \] This can be rearranged to find \( \frac{dV}{dT} \): \[ \frac{dV}{dT} = \frac{R}{2kV} \] ### Step 4: Apply the First Law of Thermodynamics According to the first law of thermodynamics: \[ dQ = dU + dW \] For one mole of gas, the change in internal energy \( dU \) is given by: \[ dU = C_v dT \] The work done \( dW \) during an expansion is: \[ dW = pdV \] Substituting \( p = kV \) gives: \[ dW = kV dV \] ### Step 5: Substitute \( dW \) and \( dU \) into the First Law Now we can write: \[ dQ = C_v dT + kV dV \] Substituting \( dV \) from Step 3: \[ dQ = C_v dT + kV \left(\frac{R}{2kV}\right) dT \] This simplifies to: \[ dQ = C_v dT + \frac{R}{2} dT \] ### Step 6: Factor out \( dT \) to find \( C \) Factoring \( dT \) out gives: \[ dQ = \left(C_v + \frac{R}{2}\right) dT \] Thus, the molar heat capacity \( C \) for the process is: \[ C = C_v + \frac{R}{2} \] ### Conclusion We have shown that the molar heat capacity of the gas for the process is given by: \[ C = C_v + \frac{R}{2} \]

To solve the problem, we need to derive the expression for the molar heat capacity \( C \) of an ideal gas undergoing a process defined by the equation \( p = kV \). Here’s a step-by-step solution: ### Step 1: Start with the Ideal Gas Law The ideal gas law is given by: \[ PV = nRT \] For one mole of gas (\( n = 1 \)), this simplifies to: ...
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DC PANDEY ENGLISH-THERMOMETRY,THERMAL EXPANSION & KINETIC THEORY OF GASES-Level 1 Subjective
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