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The volume of a diatomic gas (gamma = 7/...

The volume of a diatomic gas `(gamma = 7//5)` is increased two times in a polytropic process with molar heat capacity ` C = R`. How many times will the rate of collision of molecules against the wall of the vessel be reduced as a result of this process?

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To solve the problem, we need to determine how many times the rate of collision of molecules against the wall of the vessel is reduced when the volume of a diatomic gas is increased two times in a polytropic process with a given molar heat capacity. ### Step-by-Step Solution: 1. **Identify Given Values:** - For a diatomic gas, \(\gamma = \frac{7}{5}\). - Molar heat capacity \(C = R\). - The volume is increased two times: \(V_f = 2V_i\). 2. **Determine the Polytropic Process Relationship:** - In a polytropic process, the relationship is given by \(PV^x = \text{constant}\). - We need to find the value of \(x\) using the heat capacity relation: \[ C = \frac{R}{1 - x} + \frac{R}{\gamma - 1} \] - Substituting \(C = R\) and \(\gamma = \frac{7}{5}\): \[ R = \frac{R}{1 - x} + \frac{R}{\frac{7}{5} - 1} \] - Simplifying gives: \[ R = \frac{R}{1 - x} + \frac{5R}{2} \] - Rearranging leads to: \[ 1 = \frac{1}{1 - x} + \frac{5}{2} \] - This simplifies to: \[ 1 - x = \frac{2}{3} \implies x = \frac{5}{3} \] 3. **Find the Final Pressure:** - Using the polytropic relation \(PV^{\frac{5}{3}} = \text{constant}\): - If \(V_f = 2V_i\), then: \[ P_f (2V_i)^{\frac{5}{3}} = P_i V_i^{\frac{5}{3}} \] - Rearranging gives: \[ P_f = P_i \left(\frac{V_i^{\frac{5}{3}}}{(2V_i)^{\frac{5}{3}}}\right) = P_i \left(\frac{1}{2^{\frac{5}{3}}}\right) \] 4. **Calculate the Rate of Collision:** - The rate of collision \(Z\) is proportional to the pressure \(P\) and the root mean square speed \(V_{rms}\): \[ Z \propto \frac{P}{V_{rms}} \] - The \(V_{rms}\) is given by: \[ V_{rms} \propto \sqrt{\frac{P}{V}} \] - Therefore, we can express the new \(V_{rms}\): \[ V_{rms,f} = V_{rms,i} \cdot \sqrt{\frac{P_f}{P_i}} \cdot \sqrt{\frac{V_i}{2V_i}} = V_{rms,i} \cdot \sqrt{\frac{1}{2^{\frac{5}{3}}}} \cdot \sqrt{\frac{1}{2}} = V_{rms,i} \cdot \frac{1}{2^{\frac{5}{6}}} \] 5. **Final Rate of Collision Calculation:** - Substituting \(P_f\) and \(V_{rms,f}\) into the collision rate equation: \[ Z_f \propto \frac{P_f}{V_{rms,f}} = \frac{P_i \cdot \frac{1}{2^{\frac{5}{3}}}}{V_{rms,i} \cdot \frac{1}{2^{\frac{5}{6}}}} = Z_i \cdot \frac{1}{2^{\frac{5}{3}}} \cdot 2^{\frac{5}{6}} = Z_i \cdot 2^{-\frac{5}{3} + \frac{5}{6}} = Z_i \cdot 2^{-\frac{10}{6} + \frac{5}{6}} = Z_i \cdot 2^{-\frac{5}{6}} \] 6. **Conclusion:** - The rate of collision is reduced by a factor of \(2^{\frac{5}{6}}\). ### Final Answer: The rate of collision of molecules against the wall of the vessel is reduced by a factor of \(2^{\frac{5}{6}}\).

To solve the problem, we need to determine how many times the rate of collision of molecules against the wall of the vessel is reduced when the volume of a diatomic gas is increased two times in a polytropic process with a given molar heat capacity. ### Step-by-Step Solution: 1. **Identify Given Values:** - For a diatomic gas, \(\gamma = \frac{7}{5}\). - Molar heat capacity \(C = R\). - The volume is increased two times: \(V_f = 2V_i\). ...
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