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One mole of a monoatomic ideal gas is ta...

One mole of a monoatomic ideal gas is taken through the cycle shown in figure.
``
`ArarrB` Adiabatic expansion
`BrarrC` Cooling at constant volume
`CrarrD` Adiabatic compression.
`DrarrA` Heating at constant volume
The pressure and temperature at A,B etc., are denoted by `p_A, T_A, p_B, T_B` etc. respectively.
Given, `T_A=1000K`, `p_B=(2/3)p_A` and `p_C=(1/3)p_A`. Calculate
(a) the work done by the gas in the process `ArarrB`
(b) the heat lost by the gas in the process `BrarrC`
Given, `(2/3)^0.4=0.85` and `R=8.31J//mol-K`

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To solve the given problem step by step, we will break it down into two parts as per the question requirements: ### Part (a): Work Done by the Gas in the Process A to B 1. **Identify the Process**: The process from A to B is an adiabatic expansion. For an adiabatic process, the work done \( W \) can be calculated using the formula: \[ W = \frac{P_2 V_2 - P_1 V_1}{\gamma - 1} \] where \( P_1 \) and \( P_2 \) are the pressures at states A and B, \( V_1 \) and \( V_2 \) are the volumes at states A and B, and \( \gamma \) is the heat capacity ratio. 2. **Use the Ideal Gas Law**: Since we do not have the volumes directly, we can use the ideal gas law \( PV = nRT \) to express the volumes in terms of pressure and temperature: \[ V = \frac{nRT}{P} \] Thus, \[ V_A = \frac{nRT_A}{P_A}, \quad V_B = \frac{nRT_B}{P_B} \] 3. **Calculate the Pressures**: We know that: - \( T_A = 1000 \, K \) - \( P_B = \frac{2}{3} P_A \) 4. **Calculate the Temperature at B**: Using the adiabatic relation \( P_1 V_1^\gamma = P_2 V_2^\gamma \): \[ P_A \left(\frac{nRT_A}{P_A}\right)^\gamma = P_B \left(\frac{nRT_B}{P_B}\right)^\gamma \] This simplifies to: \[ T_A^\gamma P_A^{1-\gamma} = T_B^\gamma P_B^{1-\gamma} \] We can solve for \( T_B \) using the ratio of pressures: \[ T_B = T_A \left(\frac{P_B}{P_A}\right)^{\frac{\gamma - 1}{\gamma}} = 1000 \left(\frac{2}{3}\right)^{\frac{2}{5}} \approx 850 \, K \] 5. **Calculate Work Done**: Now substituting the values back into the work done formula: \[ W = \frac{P_B V_B - P_A V_A}{\gamma - 1} \] Using \( V_A \) and \( V_B \) from the ideal gas law: \[ W = \frac{\left(\frac{2}{3} P_A \cdot \frac{nR \cdot 850}{\frac{2}{3} P_A}\right) - \left(P_A \cdot \frac{nR \cdot 1000}{P_A}\right)}{\frac{5}{3} - 1} \] Simplifying this gives: \[ W = \frac{nR(850 - 1000)}{\frac{2}{3}} = \frac{nR(-150)}{\frac{2}{3}} = -225nR \] For \( n = 1 \) mole and \( R = 8.31 \, J/(mol \cdot K) \): \[ W = -225 \cdot 8.31 \approx -1875 \, J \] Since work done by the gas is positive during expansion, we take the absolute value: \[ W \approx 1875 \, J \] ### Part (b): Heat Lost by the Gas in the Process B to C 1. **Identify the Process**: The process from B to C is a cooling at constant volume (isochoric process). The heat lost \( Q \) can be calculated using: \[ Q = n C_v \Delta T \] where \( C_v \) is the molar heat capacity at constant volume. 2. **Calculate \( C_v \)**: For a monoatomic ideal gas: \[ C_v = \frac{3}{2} R \] 3. **Determine the Temperature Change**: We need to find \( T_C \): Using the relation for constant volume: \[ \frac{P_B}{T_B} = \frac{P_C}{T_C} \] Given \( P_C = \frac{1}{3} P_A \) and substituting \( P_B = \frac{2}{3} P_A \): \[ T_C = T_B \cdot \frac{P_C}{P_B} = 850 \cdot \frac{1/3}{2/3} = 850 \cdot \frac{1}{2} = 425 \, K \] 4. **Calculate \( \Delta T \)**: \[ \Delta T = T_C - T_B = 425 - 850 = -425 \, K \] 5. **Calculate Heat Lost**: \[ Q = n C_v \Delta T = 1 \cdot \frac{3}{2} R \cdot (-425) \] Substituting \( R = 8.31 \): \[ Q = \frac{3}{2} \cdot 8.31 \cdot (-425) \approx -5312.25 \, J \] The heat lost is approximately \( 5312.25 \, J \). ### Summary of Results: - (a) Work done by the gas in the process A to B: \( 1875 \, J \) - (b) Heat lost by the gas in the process B to C: \( 5312.25 \, J \)

To solve the given problem step by step, we will break it down into two parts as per the question requirements: ### Part (a): Work Done by the Gas in the Process A to B 1. **Identify the Process**: The process from A to B is an adiabatic expansion. For an adiabatic process, the work done \( W \) can be calculated using the formula: \[ W = \frac{P_2 V_2 - P_1 V_1}{\gamma - 1} \] ...
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