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In the relation: P=(alpha)/(beta)e^(-(al...

In the relation: `P=(alpha)/(beta)e^(-(alphaZ)/(ktheta)),P` is pressure `Z` is distance `k` is Boltzmann constant and `theta` is the temperature. The dimensional formula of `beta` will be

A

`[M^(0)L^(2)T^(0)]`

B

`[ML^(2)T^(1)]`

C

`[ML^(0)T^(-1)]`

D

`[M^(0)L^(2)T^(-1)]`

Text Solution

AI Generated Solution

The correct Answer is:
To find the dimensional formula of \(\beta\) in the relation \[ P = \frac{\alpha}{\beta} e^{-\frac{\alpha Z}{k \theta}}, \] we need to ensure that the terms in the exponent are dimensionless. Let's break down the steps to derive the dimensional formula for \(\beta\). ### Step 1: Understand the Terms - \(P\) is pressure. - \(Z\) is distance. - \(k\) is the Boltzmann constant. - \(\theta\) is temperature. - \(\alpha\) and \(\beta\) are constants. ### Step 2: Identify the Dimensions 1. **Pressure (\(P\))**: The dimensional formula for pressure is given by: \[ [P] = [M L^{-1} T^{-2}] \] 2. **Distance (\(Z\))**: The dimensional formula for distance is: \[ [Z] = [L] \] 3. **Boltzmann Constant (\(k\))**: The dimensional formula for the Boltzmann constant is: \[ [k] = [M L^2 T^{-2} K^{-1}] \] where \(K\) represents temperature in Kelvin. 4. **Temperature (\(\theta\))**: The dimensional formula for temperature is: \[ [\theta] = [K] \] ### Step 3: Ensure the Exponent is Dimensionless For the expression \(-\frac{\alpha Z}{k \theta}\) to be dimensionless, the dimensions of \(\alpha Z\) must equal the dimensions of \(k \theta\). Therefore, we can write: \[ [\alpha Z] = [k \theta] \] This implies: \[ [\alpha][Z] = [k][\theta] \] Substituting the dimensions we have: \[ [\alpha][L] = [M L^2 T^{-2} K^{-1}][K] \] This simplifies to: \[ [\alpha][L] = [M L^2 T^{-2}] \] ### Step 4: Solve for \(\alpha\) From the above equation, we can isolate \([\alpha]\): \[ [\alpha] = \frac{[M L^2 T^{-2}]}{[L]} = [M L T^{-2}] \] ### Step 5: Relate \(\alpha\) and \(\beta\) From the original equation, we have: \[ P = \frac{\alpha}{\beta} \] Rearranging gives: \[ \beta = \frac{\alpha}{P} \] ### Step 6: Substitute Dimensions Now substituting the dimensions we found: \[ [\beta] = \frac{[M L T^{-2}]}{[M L^{-1} T^{-2}]} \] This simplifies to: \[ [\beta] = [M L T^{-2}] \cdot [M^{-1} L^{1} T^{2}] = [M^{0} L^{2} T^{0}] = [L^2] \] ### Final Result Thus, the dimensional formula for \(\beta\) is: \[ [\beta] = [L^2] \]
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