In the relation: `P=(alpha)/(beta)e^(-(alphaZ)/(ktheta)),P` is pressure `Z` is distance `k` is Boltzmann constant and `theta` is the temperature. The dimensional formula of `beta` will be
A
`[M^(0)L^(2)T^(0)]`
B
`[ML^(2)T^(1)]`
C
`[ML^(0)T^(-1)]`
D
`[M^(0)L^(2)T^(-1)]`
Text Solution
AI Generated Solution
The correct Answer is:
To find the dimensional formula of \(\beta\) in the relation
\[
P = \frac{\alpha}{\beta} e^{-\frac{\alpha Z}{k \theta}},
\]
we need to ensure that the terms in the exponent are dimensionless. Let's break down the steps to derive the dimensional formula for \(\beta\).
### Step 1: Understand the Terms
- \(P\) is pressure.
- \(Z\) is distance.
- \(k\) is the Boltzmann constant.
- \(\theta\) is temperature.
- \(\alpha\) and \(\beta\) are constants.
### Step 2: Identify the Dimensions
1. **Pressure (\(P\))**: The dimensional formula for pressure is given by:
\[
[P] = [M L^{-1} T^{-2}]
\]
2. **Distance (\(Z\))**: The dimensional formula for distance is:
\[
[Z] = [L]
\]
3. **Boltzmann Constant (\(k\))**: The dimensional formula for the Boltzmann constant is:
\[
[k] = [M L^2 T^{-2} K^{-1}]
\]
where \(K\) represents temperature in Kelvin.
4. **Temperature (\(\theta\))**: The dimensional formula for temperature is:
\[
[\theta] = [K]
\]
### Step 3: Ensure the Exponent is Dimensionless
For the expression \(-\frac{\alpha Z}{k \theta}\) to be dimensionless, the dimensions of \(\alpha Z\) must equal the dimensions of \(k \theta\). Therefore, we can write:
\[
[\alpha Z] = [k \theta]
\]
This implies:
\[
[\alpha][Z] = [k][\theta]
\]
Substituting the dimensions we have:
\[
[\alpha][L] = [M L^2 T^{-2} K^{-1}][K]
\]
This simplifies to:
\[
[\alpha][L] = [M L^2 T^{-2}]
\]
### Step 4: Solve for \(\alpha\)
From the above equation, we can isolate \([\alpha]\):
\[
[\alpha] = \frac{[M L^2 T^{-2}]}{[L]} = [M L T^{-2}]
\]
### Step 5: Relate \(\alpha\) and \(\beta\)
From the original equation, we have:
\[
P = \frac{\alpha}{\beta}
\]
Rearranging gives:
\[
\beta = \frac{\alpha}{P}
\]
### Step 6: Substitute Dimensions
Now substituting the dimensions we found:
\[
[\beta] = \frac{[M L T^{-2}]}{[M L^{-1} T^{-2}]}
\]
This simplifies to:
\[
[\beta] = [M L T^{-2}] \cdot [M^{-1} L^{1} T^{2}] = [M^{0} L^{2} T^{0}] = [L^2]
\]
### Final Result
Thus, the dimensional formula for \(\beta\) is:
\[
[\beta] = [L^2]
\]
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