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The molar heat capacity in a process of ...

The molar heat capacity in a process of a diatomic gas if it does a work of `Q/4` when a heat of `Q` is supplied to it is

A

`(2)/(5)R`

B

`(5)/(2)R`

C

`(10)/(3)R`

D

`(6)/(7)R`

Text Solution

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The correct Answer is:
To find the molar heat capacity \( C \) of a diatomic gas when it does work of \( \frac{Q}{4} \) upon receiving heat \( Q \), we can follow these steps: ### Step 1: Apply the First Law of Thermodynamics The first law of thermodynamics states: \[ Q = W + \Delta U \] Where: - \( Q \) is the heat supplied, - \( W \) is the work done by the system, - \( \Delta U \) is the change in internal energy. ### Step 2: Substitute the Given Values We know that the work done \( W = \frac{Q}{4} \). Substituting this into the first law gives: \[ \Delta U = Q - W = Q - \frac{Q}{4} = \frac{3Q}{4} \] ### Step 3: Relate Change in Internal Energy to Temperature Change For a diatomic gas, the change in internal energy can also be expressed as: \[ \Delta U = nR \Delta T \left(\frac{1}{\gamma - 1}\right) \] Where: - \( n \) is the number of moles, - \( R \) is the universal gas constant, - \( \Delta T \) is the change in temperature, - \( \gamma \) is the specific heat ratio, which for a diatomic gas is \( \frac{7}{5} \). ### Step 4: Substitute \( \gamma \) into the Equation Substituting \( \gamma = \frac{7}{5} \) into the equation gives: \[ \Delta U = nR \Delta T \left(\frac{1}{\frac{7}{5} - 1}\right) = nR \Delta T \left(\frac{1}{\frac{2}{5}}\right) = \frac{5}{2} nR \Delta T \] ### Step 5: Set the Two Expressions for \( \Delta U \) Equal Now we equate the two expressions for \( \Delta U \): \[ \frac{3Q}{4} = \frac{5}{2} nR \Delta T \] ### Step 6: Solve for \( n \Delta T \) Rearranging gives: \[ nR \Delta T = \frac{3Q}{4} \cdot \frac{2}{5} = \frac{3Q}{10} \] ### Step 7: Relate Heat Supplied to Molar Heat Capacity The heat supplied can also be expressed as: \[ Q = nC \Delta T \] Substituting \( n \Delta T \) from the previous step: \[ Q = nC \Delta T \implies Q = nC \left(\frac{3Q}{10R}\right) \] ### Step 8: Solve for Molar Heat Capacity \( C \) Cancelling \( Q \) from both sides (assuming \( Q \neq 0 \)): \[ 1 = nC \left(\frac{3}{10R}\right) \implies C = \frac{10R}{3} \] ### Final Answer Thus, the molar heat capacity \( C \) of the diatomic gas is: \[ C = \frac{10R}{3} \]
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