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A vessel contains 1 mole of O2 gas (rela...

A vessel contains 1 mole of `O_2` gas (relative molar mass 32) at a temperature T. The pressure of the gas is P. An identical vessel containing one mole of He gas (relative molar mass 4) at temperature 2T has a pressure of

A

`p//8`

B

`p`

C

`2p`

D

`8p`

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The correct Answer is:
To solve the problem, we will use the Ideal Gas Law, which is given by the equation: \[ PV = nRT \] where: - \( P \) = pressure, - \( V \) = volume, - \( n \) = number of moles, - \( R \) = universal gas constant, - \( T \) = temperature in Kelvin. ### Step-by-Step Solution: 1. **Identify the Variables for the First Vessel (Oxygen)**: - Number of moles (\( n_1 \)) = 1 mole (given) - Molar mass of \( O_2 \) = 32 (not directly needed for this calculation) - Temperature (\( T_1 \)) = \( T \) (given) - Pressure (\( P_1 \)) = \( P \) (given) - Volume (\( V \)) = constant (since the vessels are identical) Using the Ideal Gas Law for the first vessel: \[ P_1 V = n_1 R T_1 \] Substituting the known values: \[ P V = 1 \cdot R \cdot T \] 2. **Identify the Variables for the Second Vessel (Helium)**: - Number of moles (\( n_2 \)) = 1 mole (given) - Molar mass of \( He \) = 4 (not directly needed for this calculation) - Temperature (\( T_2 \)) = \( 2T \) (given) - Pressure (\( P_2 \)) = ? (we need to find this) Using the Ideal Gas Law for the second vessel: \[ P_2 V = n_2 R T_2 \] Substituting the known values: \[ P_2 V = 1 \cdot R \cdot (2T) \] 3. **Set the Volumes Equal**: Since both vessels are identical, the volumes are equal: \[ P_1 V = P_2 V \] This means we can set the equations equal to each other: \[ P V = P_2 V \] 4. **Cancel the Volume**: Since \( V \) is common in both equations, we can cancel it out: \[ P = P_2 \] 5. **Relate the Pressures**: From the second vessel's equation: \[ P_2 = \frac{R \cdot (2T)}{V} \] From the first vessel's equation: \[ P = \frac{R \cdot T}{V} \] Now, we can express \( P_2 \) in terms of \( P \): \[ P_2 = 2P \] ### Final Result: The pressure of the helium gas in the second vessel is: \[ P_2 = 2P \]
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