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The relation between U, p and V for an i...

The relation between U, p and V for an ideal gas in an adiabatic process is given by relation `U=a+bpV`. Find the value of adiabatic exponent `(gamma)` of this gas.

A

`(b+1)/(b)`

B

`(b+1)/(a)`

C

`(a+1)/(b)`

D

`(a)/(a+b)`

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The correct Answer is:
To find the value of the adiabatic exponent \((\gamma)\) for an ideal gas in an adiabatic process given the relation \(U = a + bPV\), we can follow these steps: ### Step 1: Understand the relationship The internal energy \(U\) of an ideal gas in an adiabatic process is given by the equation: \[ U = a + bPV \] where \(a\) and \(b\) are constants, \(P\) is the pressure, and \(V\) is the volume. ### Step 2: Recall the first law of thermodynamics In an adiabatic process, the heat exchange \(dQ\) is zero. Therefore, the first law of thermodynamics states: \[ dU = dQ - dW \] Since \(dQ = 0\), we have: \[ dU = -dW \] ### Step 3: Express work done in terms of \(PV\) The work done \(dW\) in an adiabatic process can be expressed as: \[ dW = PdV + VdP \] For an ideal gas, we can also relate \(PV\) to temperature and the number of moles \(n\) using the ideal gas law: \[ PV = nRT \] ### Step 4: Relate \(dU\) to \(dT\) From the ideal gas law, we can express the change in internal energy \(dU\) as: \[ dU = nC_v dT \] where \(C_v\) is the molar heat capacity at constant volume. ### Step 5: Use the adiabatic condition For an adiabatic process, we know that: \[ PV^{\gamma} = \text{constant} \] This implies that: \[ d(PV^{\gamma}) = 0 \] From this, we can derive relationships between \(P\), \(V\), and \(T\). ### Step 6: Compare coefficients By comparing the expressions derived from the internal energy equation \(U = a + bPV\) with the derived expressions involving \(C_v\) and the adiabatic condition, we can find the relationship between \(b\) and \(\gamma\). ### Step 7: Solve for \(\gamma\) From the relationship derived, we find: \[ \frac{1}{b} = \gamma - 1 \] Thus, rearranging gives: \[ \gamma = 1 + \frac{1}{b} \] ### Final Result The value of the adiabatic exponent \(\gamma\) is: \[ \gamma = 1 + \frac{1}{b} \]
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