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The shortest wavelength of the Brackett ...

The shortest wavelength of the Brackett series of a hydrogen-like atom (atomic number of `Z` ) is the same as the shortest wavelength of the Balmer series of hydrogen atom. The value of `z` is

A

2

B

3

C

4

D

6

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The correct Answer is:
To solve the problem, we need to find the atomic number \( Z \) of a hydrogen-like atom for which the shortest wavelength of the Brackett series is the same as that of the Balmer series of hydrogen. ### Step-by-Step Solution: 1. **Understand the Wavelength Formula**: The wavelength \( \lambda \) for a transition in a hydrogen-like atom can be expressed using the formula: \[ \frac{1}{\lambda} = R Z^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R \) is the Rydberg constant, \( Z \) is the atomic number, \( n_1 \) is the lower energy level, and \( n_2 \) is the higher energy level. 2. **Calculate Wavelength for the Balmer Series of Hydrogen**: For the Balmer series in hydrogen (\( Z = 1 \)): - The lowest transition occurs from \( n_2 = \infty \) to \( n_1 = 2 \). - Plugging in the values: \[ \frac{1}{\lambda_{\text{Balmer}}} = R \cdot 1^2 \left( \frac{1}{2^2} - \frac{1}{\infty^2} \right) = R \left( \frac{1}{4} - 0 \right) = \frac{R}{4} \] Thus, we have: \[ \lambda_{\text{Balmer}} = \frac{4}{R} \] 3. **Calculate Wavelength for the Brackett Series of Hydrogen-like Atom**: For the Brackett series: - The lowest transition occurs from \( n_2 = \infty \) to \( n_1 = 4 \). - Using the formula: \[ \frac{1}{\lambda_{\text{Brackett}}} = R Z^2 \left( \frac{1}{4^2} - \frac{1}{\infty^2} \right) = R Z^2 \left( \frac{1}{16} - 0 \right) = \frac{R Z^2}{16} \] Thus, we have: \[ \lambda_{\text{Brackett}} = \frac{16}{R Z^2} \] 4. **Set the Wavelengths Equal**: According to the problem, the wavelengths are equal: \[ \lambda_{\text{Balmer}} = \lambda_{\text{Brackett}} \] Therefore: \[ \frac{4}{R} = \frac{16}{R Z^2} \] 5. **Solve for \( Z \)**: Cancel \( R \) from both sides: \[ 4 = \frac{16}{Z^2} \] Rearranging gives: \[ Z^2 = \frac{16}{4} = 4 \] Taking the square root: \[ Z = 2 \] ### Final Answer: The value of \( Z \) is \( 2 \). ---
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