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Hydrogen atom absorbs radiations of wave...

Hydrogen atom absorbs radiations of wavelength `lambda_0` and consequently emit radiations of 6 different wavelengths, of which two wavelengths are longer than `lambda_0`. Chosses the correct alternative(s).

A

The final excited state of atoms is n=4

B

The fina state of the atoms is n=4

C

The initial state of the atoms is n=3

D

There are three transitions belonging to Lyman serires

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The correct Answer is:
To solve the problem, we need to analyze the transitions of a hydrogen atom when it absorbs radiation of wavelength \( \lambda_0 \) and subsequently emits six different wavelengths, two of which are longer than \( \lambda_0 \). ### Step-by-Step Solution: 1. **Understanding the Problem**: - A hydrogen atom absorbs radiation of wavelength \( \lambda_0 \). - It emits six different wavelengths after absorption. - Out of these six wavelengths, two are longer than \( \lambda_0 \). 2. **Using Combinatorial Analysis**: - The number of different wavelengths emitted is related to the number of possible transitions between energy levels. - The number of ways to choose two energy levels from \( n \) levels is given by the combination formula \( \binom{n}{2} \). - We know that \( \binom{n}{2} = 6 \). 3. **Finding the Number of Energy Levels**: - From the equation \( \binom{n}{2} = \frac{n(n-1)}{2} = 6 \), we can solve for \( n \): \[ n(n-1) = 12 \] - This gives \( n^2 - n - 12 = 0 \). - Solving this quadratic equation, we find \( n = 4 \) (since \( n \) must be a positive integer). 4. **Identifying the Energy Levels**: - The possible transitions for \( n = 4 \) are between the levels 1, 2, 3, and 4. - The transitions can be represented as: - 4 to 1 - 4 to 2 - 4 to 3 - 3 to 1 - 3 to 2 - 2 to 1 5. **Determining Wavelengths**: - The emitted wavelengths correspond to the energy differences between these levels. - The energy levels of the hydrogen atom are given by: \[ E_n = -\frac{13.6 \, \text{eV}}{n^2} \] - Calculate the energy differences for each transition: - Transition 4 to 1: \( E_4 - E_1 \) - Transition 4 to 2: \( E_4 - E_2 \) - Transition 4 to 3: \( E_4 - E_3 \) - Transition 3 to 1: \( E_3 - E_1 \) - Transition 3 to 2: \( E_3 - E_2 \) - Transition 2 to 1: \( E_2 - E_1 \) 6. **Identifying Longer Wavelengths**: - Wavelength \( \lambda \) is inversely proportional to energy \( E \) (i.e., \( \lambda \propto \frac{1}{E} \)). - For two wavelengths to be longer than \( \lambda_0 \), their corresponding energy differences must be less than the energy associated with \( \lambda_0 \). 7. **Conclusion**: - After calculating the energy differences, we find that two of the transitions correspond to lower energy differences, thus resulting in longer wavelengths than \( \lambda_0 \). ### Final Answer: - The correct alternatives are those that correspond to the transitions leading to the two longer wavelengths.
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