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A target element A is bombarded with electrons and the wavelengths of the characterstic spectrum are measured. A second characteristic spectrum is also obtained , because of an impurity in the target. The wavelengths of the `K_(alpha)` lines are 196 pm (element A) and 169 pm (impurity). If the atomic number of impurity is `z=(10lambda-1)` . Find the value of `lambda` . (atomic number of element A is 27).

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To solve the problem, we will use Moseley's law, which relates the wavelength of the characteristic X-rays emitted by an atom to its atomic number. The law states that the wavelength (λ) is inversely proportional to the square of the atomic number (Z) of the element. ### Step-by-Step Solution: 1. **Understanding Moseley's Law**: According to Moseley's law, the wavelength of the Kα line can be expressed as: \[ \lambda = \frac{K}{Z - b^2} \] where \( K \) is a constant and \( b \) is a constant that can be taken as 1 for Kα lines. 2. **Setting Up the Equations**: For element A with atomic number \( Z_A = 27 \): \[ \lambda_1 = \frac{K}{27 - 1^2} = \frac{K}{26} \] For the impurity with atomic number \( Z = 10\lambda - 1 \): \[ \lambda_2 = \frac{K}{(10\lambda - 1) - 1^2} = \frac{K}{10\lambda - 2} \] 3. **Taking the Ratio of Wavelengths**: The ratio of the wavelengths for element A and the impurity is given by: \[ \frac{\lambda_1}{\lambda_2} = \frac{K/26}{K/(10\lambda - 2)} \] Simplifying this gives: \[ \frac{\lambda_1}{\lambda_2} = \frac{10\lambda - 2}{26} \] 4. **Substituting the Given Wavelengths**: We know: \[ \lambda_1 = 196 \text{ pm} = 196 \times 10^{-12} \text{ m} \] \[ \lambda_2 = 169 \text{ pm} = 169 \times 10^{-12} \text{ m} \] Thus, we can write: \[ \frac{196 \times 10^{-12}}{169 \times 10^{-12}} = \frac{10\lambda - 2}{26} \] The \( 10^{-12} \) cancels out: \[ \frac{196}{169} = \frac{10\lambda - 2}{26} \] 5. **Cross-Multiplying**: Cross-multiplying gives: \[ 196 \cdot 26 = 169 \cdot (10\lambda - 2) \] 6. **Calculating the Left Side**: Calculate \( 196 \cdot 26 \): \[ 196 \cdot 26 = 5096 \] 7. **Expanding the Right Side**: Expanding the right side: \[ 1690\lambda - 338 \] 8. **Setting the Equation**: Now we have: \[ 5096 = 1690\lambda - 338 \] 9. **Solving for \( \lambda \)**: Rearranging gives: \[ 1690\lambda = 5096 + 338 \] \[ 1690\lambda = 5434 \] \[ \lambda = \frac{5434}{1690} \approx 3.22 \] 10. **Final Answer**: Rounding gives \( \lambda \approx 3 \). ### Conclusion: The value of \( \lambda \) is approximately **3**.
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