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The dimensional formula for molar therma...

The dimensional formula for molar thermal capacity is same as that of

A

gas constant

B

specific heat

C

Boltzmann's constant

D

Stefan's constant

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The correct Answer is:
To find the dimensional formula for molar thermal capacity and determine what it is equivalent to, we can follow these steps: ### Step-by-Step Solution: 1. **Understand Molar Thermal Capacity**: Molar thermal capacity (C) is defined as the amount of heat required to raise the temperature of one mole of a substance by one degree Celsius (or one Kelvin). 2. **Formula for Molar Thermal Capacity**: Molar thermal capacity can be expressed in terms of work done (W) and temperature (T). The formula is: \[ C = \frac{W}{T \cdot N_A} \] where \( N_A \) is Avogadro's number. 3. **Work Done by a Gas**: The work done (W) by a gas can be expressed using the ideal gas equation: \[ W = P \cdot V \] From the ideal gas equation, we know: \[ PV = nRT \] where \( n \) is the number of moles, \( R \) is the universal gas constant, and \( T \) is the temperature. 4. **Substituting Work Done**: We can substitute \( PV \) in the formula for molar thermal capacity: \[ C = \frac{nRT}{T \cdot N_A} \] 5. **Simplifying the Expression**: The temperature \( T \) in the numerator and denominator cancels out: \[ C = \frac{nR}{N_A} \] 6. **Relating to Boltzmann Constant**: The term \( \frac{R}{N_A} \) is known as the Boltzmann constant (\( k \)): \[ C = n \cdot k \] Thus, the dimensional formula for molar thermal capacity is equivalent to that of the Boltzmann constant. ### Final Answer: The dimensional formula for molar thermal capacity is the same as that of the Boltzmann constant. ---
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