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The root-mean-square (rms) speed of oxyg...

The root-mean-square (rms) speed of oxygen molecules `(O_(2))` at a certain absolute temperature is v.If the temperature is double and the oxygen gas dissociated into atomic oxygen, the rms speed would be

A

v

B

`sqrt2 v`

C

2 v

D

`2sqrt2 v`

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The correct Answer is:
To solve the problem, we need to determine the new root-mean-square (rms) speed of oxygen molecules when the temperature is doubled and the gas dissociates into atomic oxygen. ### Step-by-Step Solution: 1. **Understand the formula for rms speed**: The root-mean-square speed (Vrms) is given by the formula: \[ V_{\text{rms}} = \sqrt{\frac{3RT}{M}} \] where \( R \) is the universal gas constant, \( T \) is the absolute temperature, and \( M \) is the molar mass of the gas. 2. **Identify the initial conditions**: For diatomic oxygen (\( O_2 \)): - The molar mass \( M \) is 32 g/mol. - The initial temperature is \( T \). - The initial rms speed is \( V \). 3. **Determine the new conditions**: - The temperature is doubled: \( T' = 2T \). - The oxygen gas dissociates into atomic oxygen, which has a molar mass of \( M' = 16 \) g/mol (since each \( O_2 \) molecule splits into two \( O \) atoms). 4. **Substitute the new values into the rms speed formula**: The new rms speed \( V'_{\text{rms}} \) can be expressed as: \[ V'_{\text{rms}} = \sqrt{\frac{3R(2T)}{M'}} \] Substituting \( M' = \frac{M}{2} \) (since the molar mass of atomic oxygen is half that of molecular oxygen): \[ V'_{\text{rms}} = \sqrt{\frac{3R(2T)}{16}} = \sqrt{\frac{6RT}{16}} = \sqrt{\frac{3RT}{8}} \] 5. **Relate the new rms speed to the initial rms speed**: We can express the new rms speed in terms of the initial rms speed: \[ V'_{\text{rms}} = \sqrt{\frac{3RT}{32}} \cdot \sqrt{2} = V \cdot \sqrt{2} \] Thus, we have: \[ V'_{\text{rms}} = 2V \] 6. **Conclusion**: The new rms speed of the dissociated oxygen atoms at the doubled temperature is: \[ V'_{\text{rms}} = 2V \] Therefore, the correct answer is \( 2V \).

To solve the problem, we need to determine the new root-mean-square (rms) speed of oxygen molecules when the temperature is doubled and the gas dissociates into atomic oxygen. ### Step-by-Step Solution: 1. **Understand the formula for rms speed**: The root-mean-square speed (Vrms) is given by the formula: \[ V_{\text{rms}} = \sqrt{\frac{3RT}{M}} ...
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DC PANDEY ENGLISH-THERMOMETRY THERMAL EXPANSION AND KINETIC THEORY OF GASES-Check point 14.3
  1. Which one of the following is not an assumption in the kinetic theory ...

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  2. Vapor is injected at a uniform rate in a closed vessel which was initi...

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  3. The average velocity of molecules of a gas of molecular weight (M) at ...

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  4. For gas at a temperature T the root-mean-square speed v(rms), the most...

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  5. The average kinetic energy of a gas molecule is

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  6. KE per unit volume is E. The pressure exerted by the gas is given by

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  7. If at the same temperature and pressure, the densities of two diatomic...

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  8. Two vessels A and B having equal volume contain equal masses of hydrog...

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  9. A vessel contains 1 mole of O(2) gas (molar mass 32) at a temperature ...

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  10. What will be the temperature when the rms velocity is double of that a...

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  11. By what factor the rms velocity will change, if the temperature is rai...

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  12. The velocities of three molecules are 3v, 4v and 5v. Calculate their r...

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  13. The temperature at which the root mean squres speed of a gas will be h...

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  14. Four molecules of gas have speeds 1,2,3 and 4 km//s.The value of the r...

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  15. A sealed container with negiligible coefficient of volumetric expansio...

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  16. The gases carbon-monoxide (CO) and nitrogen at the same temperature ha...

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  17. Pressure of an ideal gas is increased by keeping temperature constant....

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  18. Some gas at 300K is enclosed in a container. Now the container is plac...

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  19. The root-mean-square (rms) speed of oxygen molecules (O(2)) at a certa...

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  20. The molecules of a given mass of a gas have rms velocity of 200 m//s a...

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