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An electron jumps from the 4th orbit to ...

An electron jumps from the `4th` orbit to the `2nd` orbit of hydrogen atom. Given the Rydberg's constant `R = 10^(5) cm^(-1)`. The frequency in `Hz` of the emitted radiation will be

A

`(3)/(16)xx10^(5)`

B

`(3)/(16)xx10^(15)`

C

`(9)/(16)xx10^(15)`

D

`(3)/(4)xx10^(15)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the frequency of the emitted radiation when an electron jumps from the 4th orbit to the 2nd orbit in a hydrogen atom, we can follow these steps: ### Step 1: Identify the given data - Rydberg's constant, \( R = 10^5 \, \text{cm}^{-1} \) - Initial orbit (n2) = 4 - Final orbit (n1) = 2 ### Step 2: Use the Rydberg formula The Rydberg formula for the wavelength of the emitted radiation is given by: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] Substituting the values into the formula: \[ \frac{1}{\lambda} = 10^5 \left( \frac{1}{2^2} - \frac{1}{4^2} \right) \] ### Step 3: Calculate the terms inside the parentheses Calculating \( \frac{1}{2^2} \) and \( \frac{1}{4^2} \): \[ \frac{1}{2^2} = \frac{1}{4} = 0.25 \] \[ \frac{1}{4^2} = \frac{1}{16} = 0.0625 \] Now, substituting these values: \[ \frac{1}{\lambda} = 10^5 \left( 0.25 - 0.0625 \right) = 10^5 \left( 0.1875 \right) \] ### Step 4: Calculate \( \frac{1}{\lambda} \) \[ \frac{1}{\lambda} = 10^5 \times 0.1875 = 18750 \, \text{cm}^{-1} \] ### Step 5: Find the wavelength \( \lambda \) Taking the reciprocal to find \( \lambda \): \[ \lambda = \frac{1}{18750} \, \text{cm} \] ### Step 6: Convert wavelength to meters To convert from centimeters to meters: \[ \lambda = \frac{1}{18750} \times 10^{-2} \, \text{m} = \frac{10^{-2}}{18750} \, \text{m} \] ### Step 7: Calculate the frequency \( f \) Using the speed of light \( c = 3 \times 10^8 \, \text{m/s} \), we can find the frequency using the formula: \[ f = \frac{c}{\lambda} \] Substituting the values: \[ f = \frac{3 \times 10^8}{\frac{10^{-2}}{18750}} = 3 \times 10^8 \times \frac{18750}{10^{-2}} = 3 \times 10^8 \times 1875000 \] ### Step 8: Simplify the frequency calculation Calculating \( 3 \times 1875000 \): \[ 3 \times 1875000 = 5625000 \] Thus, \[ f = 5625000 \times 10^{10} \, \text{Hz} = 5.625 \times 10^{15} \, \text{Hz} \] ### Final Answer The frequency of the emitted radiation is: \[ f = \frac{9}{16} \times 10^{15} \, \text{Hz} \]
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