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The shortest wavelength of the Brackett ...

The shortest wavelength of the Brackett series of a hydrogen-like atom (atomic number of `Z` ) is the same as the shortest wavelength of the Balmer series of hydrogen atom. The value of `z` is

A

3

B

4

C

5

D

2

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The correct Answer is:
To solve the problem, we need to find the atomic number \( Z \) of a hydrogen-like atom, given that the shortest wavelength of the Brackett series of this atom is the same as the shortest wavelength of the Balmer series of a hydrogen atom. ### Step-by-Step Solution: 1. **Understanding the Series**: - The Brackett series transitions occur when an electron falls to the \( n = 4 \) energy level. - The Balmer series transitions occur when an electron falls to the \( n = 2 \) energy level. 2. **Formula for Wavelength**: - The formula for the wavelength in terms of wave number is given by: \[ \frac{1}{\lambda} = R Z^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] - Where \( R \) is the Rydberg constant, \( Z \) is the atomic number, \( n_1 \) is the lower energy level, and \( n_2 \) is the higher energy level. 3. **Brackett Series for Hydrogen-like Atom**: - For the Brackett series, \( n_1 = 4 \) and \( n_2 \) can be \( 5, 6, \ldots \). The shortest wavelength corresponds to \( n_2 \to \infty \): \[ \frac{1}{\lambda_{Brackett}} = R Z^2 \left( \frac{1}{4^2} - 0 \right) = R Z^2 \left( \frac{1}{16} \right) \] 4. **Balmer Series for Hydrogen**: - For the Balmer series, \( n_1 = 2 \) and \( n_2 \) can be \( 3, 4, \ldots \). The shortest wavelength corresponds to \( n_2 \to \infty \): \[ \frac{1}{\lambda_{Balmer}} = R \left( \frac{1}{2^2} - 0 \right) = R \left( \frac{1}{4} \right) \] 5. **Setting the Wavelengths Equal**: - Since the shortest wavelengths are equal: \[ R Z^2 \left( \frac{1}{16} \right) = R \left( \frac{1}{4} \right) \] 6. **Canceling \( R \)**: - We can cancel \( R \) from both sides: \[ Z^2 \left( \frac{1}{16} \right) = \frac{1}{4} \] 7. **Solving for \( Z^2 \)**: - Rearranging gives: \[ Z^2 = 4 \] 8. **Finding \( Z \)**: - Taking the square root: \[ Z = 2 \] ### Final Answer: The value of \( Z \) is \( 2 \).

To solve the problem, we need to find the atomic number \( Z \) of a hydrogen-like atom, given that the shortest wavelength of the Brackett series of this atom is the same as the shortest wavelength of the Balmer series of a hydrogen atom. ### Step-by-Step Solution: 1. **Understanding the Series**: - The Brackett series transitions occur when an electron falls to the \( n = 4 \) energy level. - The Balmer series transitions occur when an electron falls to the \( n = 2 \) energy level. ...
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